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For a certain reaction Ato products, the...

For a certain reaction `Ato` products, the `t_(1//2)` as a function of `[A]_0` is given as below:
`{:([A]_0(M),0.1,0.025),(t_(1//2),100,50):}`
Which of the following is true :

A

The order of `1/2`

B

`t_(1//2)`would be `100sqrt10` min for `[A]_0=1` M

C

The order is 1

D

`t_(1//2)`would be `100` min for `[A]_0=1` M

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the relationship between the half-life \( t_{1/2} \) and the initial concentration \( [A]_0 \) of the reactant \( A \). The relationship is given by the formula: \[ t_{1/2} \propto [A]_0^{(1-n)} \] where \( n \) is the order of the reaction. ### Step-by-Step Solution: 1. **Set Up the Proportionality**: We have two sets of data: - For \( [A]_0 = 0.1 \, M \), \( t_{1/2} = 100 \, \text{minutes} \) - For \( [A]_0 = 0.025 \, M \), \( t_{1/2} = 50 \, \text{minutes} \) Using the proportionality, we can write: \[ t_{1/2} \propto [A]_0^{(1-n)} \] 2. **Write the Equations**: From the first data point: \[ 100 \propto (0.1)^{(1-n)} \] From the second data point: \[ 50 \propto (0.025)^{(1-n)} \] 3. **Form Ratios**: Taking the ratio of the two equations: \[ \frac{100}{50} = \frac{(0.1)^{(1-n)}}{(0.025)^{(1-n)}} \] Simplifying the left side gives: \[ 2 = \frac{(0.1)^{(1-n)}}{(0.025)^{(1-n)}} \] 4. **Expressing the Concentrations**: We can express \( 0.1 \) and \( 0.025 \) as: \[ 0.1 = \frac{1}{10} \quad \text{and} \quad 0.025 = \frac{1}{40} \] Therefore, we can rewrite: \[ 0.1 = 4 \times 0.025 \] Thus, we have: \[ 2 = \left(\frac{0.1}{0.025}\right)^{(1-n)} = (4)^{(1-n)} \] 5. **Solving for \( n \)**: Taking logarithms or equating the powers gives: \[ 2 = 4^{(1-n)} \implies 2 = 2^2 \implies 1-n = 2 \implies n = -1 \] 6. **Conclusion**: The order of the reaction \( n \) is \( \frac{1}{2} \). ### Final Answer: The correct options are: 1. The order of the reaction is \( \frac{1}{2} \). 2. \( t_{1/2} \) would be \( 100 \sqrt{10} \) minutes for \( [A]_0 = 1 \, M \).

To solve the problem, we need to analyze the relationship between the half-life \( t_{1/2} \) and the initial concentration \( [A]_0 \) of the reactant \( A \). The relationship is given by the formula: \[ t_{1/2} \propto [A]_0^{(1-n)} \] where \( n \) is the order of the reaction. ...
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