Home
Class 12
CHEMISTRY
Statement-1: For A+2BtoC(rate =K[A]^(1)[...

Statement-1: For `A+2BtoC`(rate =`K[A]^(1)[B]^(0)`), the half life time of reaction is only defined when concentration of A and B are in stoichometric ratio
Statement-2 :For above reaction, half life of reaction is directly proportional to concentration of A and not to concentration of B due to its zero order.

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-2

C

Statement-1 is True, Statement-2 is False.

D

Statement-1 is False, Statement-2 is True.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to evaluate the two statements provided regarding the reaction \( A + 2B \rightarrow C \) and its half-life. ### Step-by-Step Solution: **Step 1: Analyze Statement 1** - The reaction is given as \( A + 2B \rightarrow C \). - The rate of the reaction is expressed as \( \text{rate} = k[A]^1[B]^0 \). - This implies that the rate depends only on the concentration of \( A \) and is independent of the concentration of \( B \) (since \( [B]^0 = 1 \)). - The statement claims that the half-life of the reaction is only defined when the concentrations of \( A \) and \( B \) are in a stoichiometric ratio. This is correct because if the concentration of \( B \) is significantly lower than required, it could limit the reaction, making the half-life undefined. **Conclusion for Statement 1: True** **Step 2: Analyze Statement 2** - The second statement asserts that the half-life of the reaction is directly proportional to the concentration of \( A \) and not to the concentration of \( B \) due to its zero-order nature. - However, since the reaction is first-order with respect to \( A \) (as indicated by the rate law), the half-life for a first-order reaction is given by the formula: \[ t_{1/2} = \frac{0.693}{k} \text{ (independent of concentration)} \] - Therefore, the half-life is independent of the concentration of \( A \) and does not depend on \( B \) because \( B \) does not affect the rate. **Conclusion for Statement 2: False** ### Final Answer: - Statement 1 is true, and Statement 2 is false. Therefore, the correct option is **Option 3**.

To solve the question, we need to evaluate the two statements provided regarding the reaction \( A + 2B \rightarrow C \) and its half-life. ### Step-by-Step Solution: **Step 1: Analyze Statement 1** - The reaction is given as \( A + 2B \rightarrow C \). - The rate of the reaction is expressed as \( \text{rate} = k[A]^1[B]^0 \). - This implies that the rate depends only on the concentration of \( A \) and is independent of the concentration of \( B \) (since \( [B]^0 = 1 \)). ...
Promotional Banner

Topper's Solved these Questions

  • QUALITATIVE ANALYSIS PART 1

    RESONANCE ENGLISH|Exercise A.L.P|39 Videos
  • SOLID STATE

    RESONANCE ENGLISH|Exercise PHYSICAL CHEMITRY (SOLID STATE)|45 Videos

Similar Questions

Explore conceptually related problems

How is half-life period of a reaction is inversely proportional to initial concentration for a second order reaction?

For a zero order reaction, the half-life periof is independent of the initial concentration.

For the first order reaction half-life time is ………….. on the initial concentration.

A : The rate constant of zero order reaction is equal to rate of reaction. R : t_(1//2) for zero order reaction is directly proportional to initial concentration.

5A to Product In above reaction, half-life period is directly proportional to initial concentration of reactant. The initial rate of reaction is 400 mol lit^(-1)" min"^(-1) .

Walden inversion takes place in SN^2 reaction. Half-life period of SN^2 reaction is inversely proportional to the concentration of the substrate or nucleophile or both.

If a is the initial concentration of the rectant, the half life period of the reaction of n^(th) order is inversely proportional to :

Give the relation between half life and initial concentration of a reactant in a zero order reaction

RESONANCE ENGLISH-RANK BOOSTER-All Questions
  1. Decomposition of 3A(g)to2B(g)+2C(g) follows first order kinetics.Initi...

    Text Solution

    |

  2. Assertion (A) : If the activation energy of a reaction is zero, temper...

    Text Solution

    |

  3. Statement-1: For A+2BtoC(rate =K[A]^(1)[B]^(0)), the half life time of...

    Text Solution

    |

  4. For I^(st) order decomposition of SO2Cl2(g), SO2Cl2(g)toSO2(g)+Cl2(g...

    Text Solution

    |

  5. A mixture of NO2 and N2O4 has a vapour density of 38.3 at 300K. What i...

    Text Solution

    |

  6. At N.T.P the volume of a gas is found to be 270mL. What will be the vo...

    Text Solution

    |

  7. The initial rate of zero order reaction of the gaseous equation A(g)to...

    Text Solution

    |

  8. The variation of concentration of 'A' with time in two experiments sta...

    Text Solution

    |

  9. The following data were observed for the following reaction at 25^(@)C...

    Text Solution

    |

  10. The following data were observed for the following reaction at 25^(@)C...

    Text Solution

    |

  11. The following data were observed for the following reaction at 25^(@)C...

    Text Solution

    |

  12. At N.T.P the volume of a gas is found to be 237mL. What will be the vo...

    Text Solution

    |

  13. At N.T.P the volume of a gas is found to be 250mL. What will be the vo...

    Text Solution

    |

  14. At N.T.P the volume of a gas is found to be 150mL. What will be the vo...

    Text Solution

    |

  15. For a hypotherical elementary reaction where k1/k2=1/2 Initailly on...

    Text Solution

    |

  16. For a hypotherical elementary reaction where k1/k2=1/2 Initailly on...

    Text Solution

    |

  17. For a hypotherical elementary reaction where k1/k2=1/2 Initailly on...

    Text Solution

    |

  18. At N.T.P the volume of a gas is found to be 270mL. What will be the vo...

    Text Solution

    |

  19. At N.T.P the volume of a gas is found to be 240mL. What will be the vo...

    Text Solution

    |

  20. Match order of the reaction (in List-I) with the corresponding rate co...

    Text Solution

    |