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The initial rate of zero order reaction ...

The initial rate of zero order reaction of the gaseous equation `A(g)to2B (g)` is `10^(-2) M min^(-1)` If the initial concentration of A is 0.1 M what would be concentration of B after 60 seconds ?

A

0.09 M

B

0.01 M

C

0.02 M

D

0.03 M

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The correct Answer is:
To solve the problem, we need to determine the concentration of B after 60 seconds in a zero-order reaction given by the equation \( A(g) \rightarrow 2B(g) \). ### Step-by-Step Solution: 1. **Understand the Reaction Order**: - The reaction is a zero-order reaction, which means the rate of reaction is constant and does not depend on the concentration of the reactants. 2. **Identify the Given Data**: - Initial rate of reaction \( = 10^{-2} \, \text{M min}^{-1} \) - Initial concentration of \( A \) \( = 0.1 \, \text{M} \) - Time \( t = 60 \, \text{seconds} = 1 \, \text{minute} \) 3. **Relate Rate to Concentration Change**: - For a zero-order reaction, the rate \( r \) can be expressed as: \[ r = -\frac{d[A]}{dt} = k \] - Since \( 2B \) is produced for every mole of \( A \) consumed, we can express the change in concentration of \( B \): \[ \frac{d[B]}{dt} = 2k \] 4. **Integrate the Rate Equation**: - Rearranging gives: \[ d[B] = 2k \, dt \] - Integrating from \( t = 0 \) to \( t = 1 \) minute: \[ [B] = 2k \cdot t \] - Here, \( k = 10^{-2} \, \text{M min}^{-1} \) and \( t = 1 \, \text{minute} \). 5. **Substitute Values**: - Substitute \( k \) and \( t \) into the equation: \[ [B] = 2 \cdot (10^{-2}) \cdot (1) = 0.02 \, \text{M} \] 6. **Final Concentration of B**: - The concentration of \( B \) after 60 seconds is \( 0.02 \, \text{M} \). ### Conclusion: The concentration of \( B \) after 60 seconds is \( 0.02 \, \text{M} \).

To solve the problem, we need to determine the concentration of B after 60 seconds in a zero-order reaction given by the equation \( A(g) \rightarrow 2B(g) \). ### Step-by-Step Solution: 1. **Understand the Reaction Order**: - The reaction is a zero-order reaction, which means the rate of reaction is constant and does not depend on the concentration of the reactants. 2. **Identify the Given Data**: ...
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