There is no relation between the stoichiometry of the reaction and order of the reaction, order is always experimently calculated. Monitoring of the progress of the reaction can be done by pressure measurement (`P_0,P_t` & `P_oo` are total pressure of reaction mixture at time, t=0, t=t & `t=oo`) .All following reactions in Column-1 have half life 5 minutes.

Select incorrect combination for `I^(st)` order reaction :

Options

A. (i)(i)(Q)
B. (iv)(i)(Q)
C. (iv)(iv)(S)
D. (IV)(ii)(S)

Answer

D

Explanation

In column-1 (i) &(iv) are `I^(st)` order reactions for `I^(st)` order `t_(3//4)=2t_(1//2)`