Home
Class 12
CHEMISTRY
The unit of equilibrium constant KC of a...

The unit of equilibrium constant `K_C` of a reaction is `"mol"^(-2) l^2`.For this reaction, the product concentration increases by

A

increasing the pressure

B

Lowering the temperature

C

Lowering the pressure

D

Both B and C

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the information given about the equilibrium constant \( K_C \) and how it relates to the concentrations of reactants and products in a chemical reaction. ### Step-by-Step Solution: 1. **Understanding the Unit of \( K_C \)**: The unit of the equilibrium constant \( K_C \) is given as \( \text{mol}^{-2} \, \text{l}^2 \). This indicates that the equilibrium constant is related to the concentrations of products and reactants in the reaction. 2. **Relating \( K_C \) to Reaction Stoichiometry**: The general expression for the equilibrium constant \( K_C \) for a reaction can be written as: \[ K_C = \frac{[\text{Products}]^{\text{coefficients}}}{[\text{Reactants}]^{\text{coefficients}}} \] Here, the concentration of products is raised to the power of their coefficients in the balanced equation, and the same for reactants. 3. **Determining \( \Delta n \)**: The unit \( \text{mol}^{-2} \, \text{l}^2 \) can be interpreted to find \( \Delta n \), which is the change in the number of moles of gas during the reaction. The relationship between the unit of \( K_C \) and \( \Delta n \) is: \[ K_C \propto \left( \frac{1}{[\text{Reactants}]} \right)^{\Delta n} \] Rearranging gives: \[ K_C \propto \text{mol}^{\Delta n} \, \text{l}^{-2} \] From the given unit \( \text{mol}^{-2} \, \text{l}^2 \), we can deduce: \[ \Delta n = -2 \] 4. **Interpreting \( \Delta n \)**: A \( \Delta n \) of -2 means that the number of moles of gaseous products is less than that of gaseous reactants. For example, if we have 4 moles of A gas converting into 2 moles of B gas, we have: \[ 4 \, \text{A} \rightarrow 2 \, \text{B} \] Here, the number of gaseous molecules decreases, indicating that the reaction shifts towards the products when pressure is increased. 5. **Applying Le Chatelier's Principle**: According to Le Chatelier's Principle, if we increase the pressure of a system at equilibrium, the system will shift in the direction that reduces the pressure. Since the product side has fewer moles of gas (2 moles of B) compared to the reactant side (4 moles of A), increasing the pressure will favor the formation of products. 6. **Conclusion**: Therefore, if the product concentration increases, it is due to the increase in pressure, which shifts the equilibrium towards the products. ### Final Answer: The product concentration increases by increasing the pressure.

To solve the problem, we need to analyze the information given about the equilibrium constant \( K_C \) and how it relates to the concentrations of reactants and products in a chemical reaction. ### Step-by-Step Solution: 1. **Understanding the Unit of \( K_C \)**: The unit of the equilibrium constant \( K_C \) is given as \( \text{mol}^{-2} \, \text{l}^2 \). This indicates that the equilibrium constant is related to the concentrations of products and reactants in the reaction. 2. **Relating \( K_C \) to Reaction Stoichiometry**: ...
Promotional Banner

Topper's Solved these Questions

  • QUALITATIVE ANALYSIS PART 1

    RESONANCE ENGLISH|Exercise A.L.P|39 Videos
  • SOLID STATE

    RESONANCE ENGLISH|Exercise PHYSICAL CHEMITRY (SOLID STATE)|45 Videos

Similar Questions

Explore conceptually related problems

The unit of equilibrium constant K_(c) for the reaction A+B hArr C would be

The equilibrium constant (K) for the reaction. A+2BhArr2C+D is:

Unit of equilibrium constant K_p for the reaction PCl_5(g) hArr PCl_3(g)+ Cl_2(g) is

Consider the reaction SO_(2)Cl_(2) hArr SO_(2)(g)+Cl_(2)(g) at 375^(@)C , the value of equilibrium constant for the reaction is 0.0032 . It was observed that the concentration of the three species is 0.050 mol L^(-1) each at a certain instant. Discuss what will happen in the reaction vessel?

Determine the values of equilibrium constant (K_C) and DeltaG^o for the following reaction :

A : Increasing the concentration of H_2 will increases magnitude of equilibrium constant of the reaction H_2 +I_2 hArr 2HI R: Value of K_c depends upon the concentration of reactants and products taken.

Unit of equilibrium constant (K_c) for the reaction N_2(g)+3H_2(g)

When A_2 and B_2 are allowed to react, the equilibrium constant of the reaction at 27^@C is K_C = 4 What will be the equilibrium concentration of AB?

Write the unit of equilibrium constant (K_c) for the given reaction. BaCO_3(s) hArr BaO(s) +CO_2(g)

The equilibrium constant at 298K for a reaction, A+BhArrC+D is 100. If the initial concentrations of all the four species were 1M each, then equilibirum concentration of D (in mol L^(-1) ) will be

RESONANCE ENGLISH-RANK BOOSTER-All Questions
  1. Write the number of unpaired electrons in Gd(Z=64)

    Text Solution

    |

  2. 2.4 gm of Mg (At. mass 24) will produce MgO equal to:

    Text Solution

    |

  3. The unit of equilibrium constant KC of a reaction is "mol"^(-2) l^2.Fo...

    Text Solution

    |

  4. At 1400 K, Kc=2.5xx10^(-3) for the reaction CH4(g)+2H2S(g)hArrCS2(g)+4...

    Text Solution

    |

  5. In a basic aqueous solution chloromethane undergoes a substitution rea...

    Text Solution

    |

  6. NH4COONH2 (s) hArr 2NH3(g)+CO(2)(g) If equilibrium pressure is 6 atm...

    Text Solution

    |

  7. Equilibrium constant for the given reaction is K=10^(20) at temperatur...

    Text Solution

    |

  8. A 10 litre box contains O3 and O2 at equilibrium at 2000 K. Kp=4xx10^(...

    Text Solution

    |

  9. The following two reactions: i. PCl(5)(g) hArr PCl(3)(g)+Cl(2)(g) ...

    Text Solution

    |

  10. For the chemical reaction 3X(g)+Y(g) hArr X(3)Y(g), the amount of ...

    Text Solution

    |

  11. What is the minimum mass of CaCO3(s), below which it decomposes comple...

    Text Solution

    |

  12. A polythene bag 3 litre capacity is partially filled by 1 liter of Hel...

    Text Solution

    |

  13. A solution is obtained by mixing 300 g of 25% solution and 400 g of 40...

    Text Solution

    |

  14. NH4COONH2 (s) hArr 2NH3(g)+CO(2)(g) If equilibrium pressure is 7 atm...

    Text Solution

    |

  15. Consider the following statements : (I)An increase in pressure (caus...

    Text Solution

    |

  16. How many unpaired electrons are there in Ni element ?

    Text Solution

    |

  17. Solid ammonium carbomate, NH4CO2NH2(s), dissociates into ammonia and c...

    Text Solution

    |

  18. Number of unpaired electrons in Mn^(2+) is

    Text Solution

    |

  19. 138 gm of N2O4(g) is placed in 8.2L container at 300 K.The equilibrium...

    Text Solution

    |

  20. Consider two equilibrium 2Cl2(g)+2H2O(g)hArr4HCl(g)+O2(g) and N2(g)+O...

    Text Solution

    |