Home
Class 12
CHEMISTRY
Assertion : Ag(2) S + 4 KCN hArr 2K [Ag(...

Assertion : `Ag_(2) S` + 4 KCN `hArr` `2K [Ag(CN)_(2)] + K_(2) S`
Reason : The reaction is carried out in the presence of `O_(2)` so that `K_(2)S` is oxidised to `K_(2) SO_(4)` thereby shifting the equilibrium in forward direction.

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1

C

Statement-1 is True, Statement-2 is False.

D

Statement-1 is False, Statement-2 is True.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the given question, we need to analyze the assertion and reason provided, and determine their validity and relationship. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states: \[ \text{Ag}_2\text{S} + 4 \text{KCN} \rightleftharpoons 2 \text{K[Ag(CN)}_2] + \text{K}_2\text{S} \] - This reaction indicates that silver sulfide (Ag₂S) reacts with potassium cyanide (KCN) to form potassium dicyanoargentate (K[Ag(CN)₂]) and potassium sulfide (K₂S). 2. **Validity of the Assertion**: - The assertion is true because the reaction is indeed a valid chemical reaction that occurs under certain conditions. 3. **Understanding the Reason**: - The reason states that the reaction occurs in the presence of oxygen, which oxidizes K₂S to K₂SO₄, thereby shifting the equilibrium in the forward direction. - The reaction for the oxidation of K₂S can be represented as: \[ \text{K}_2\text{S} + 2 \text{O}_2 \rightarrow \text{K}_2\text{SO}_4 \] 4. **Validity of the Reason**: - The reason is also true. The presence of oxygen can lead to the oxidation of K₂S to K₂SO₄, which would decrease the concentration of K₂S in the reaction mixture. 5. **Application of Le Chatelier's Principle**: - According to Le Chatelier's principle, if a system at equilibrium is disturbed by changing the concentration of a reactant or product, the system will shift in the direction that counteracts the disturbance. - In this case, as K₂S is consumed to form K₂SO₄, the equilibrium will shift to the right to produce more K₂S and thus favor the formation of products (K[Ag(CN)₂]). 6. **Conclusion**: - Both the assertion and the reason are true, and the reason correctly explains the assertion. Therefore, the correct answer is that both statements are true, and the reason is a correct explanation of the assertion. ### Final Answer: Both the assertion and reason are true, and the reason is the correct explanation for the assertion.

To solve the given question, we need to analyze the assertion and reason provided, and determine their validity and relationship. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states: \[ \text{Ag}_2\text{S} + 4 \text{KCN} \rightleftharpoons 2 \text{K[Ag(CN)}_2] + \text{K}_2\text{S} ...
Promotional Banner

Topper's Solved these Questions

  • QUALITATIVE ANALYSIS PART 1

    RESONANCE ENGLISH|Exercise A.L.P|39 Videos
  • SOLID STATE

    RESONANCE ENGLISH|Exercise PHYSICAL CHEMITRY (SOLID STATE)|45 Videos

Similar Questions

Explore conceptually related problems

AgCldarr+2KCN to K[Ag(CN)_(2)]+KCl

AgCldarr+2KCN to K[Ag(CN)_(2)]+KCl

For the reversible reaction NaNO_3(s) hArr NaNO_2(s) + (1/2)O_2(g) .The equilibrium shifts in forward direction

K_(2)CrO_(4) oxidises KI in the presence of KCl to I_(2) . The equivalent weight of the K_(2)CrO_(4) is

The complex K_(4)[Zn(CN)_(4)(O_(2))_(2)] is oxidised into K_(2)[Zn(CN)_(4)(O_(2))] , then whichof the following is//are correct:

The reaction of NaCl and K_(2)Cr_(2)O_(7) mixture with conc. H_(2)SO_(4) result in the formation of:

Partial pressure of O_(2) in the reaction 2Ag_(2)O(s) hArr 4Ag(s)+O_(2)(g) is

Partial pressure of O_(2) in the reaction 2Ag_(2)O(s) hArr 4Ag(s)+O_(2)(g) is

2SO_(3)hArr2SO_(2) + O_(2) . If K_(c) = 100 , alpha = 1 , half of the reaction is completed, the concentration of SO_(3) and SO_(2) are equal, the concentration of O_(2) is

NH_(4)COONH_(4)(s) hArr 2NH_(3)(g)+CO_(2)(g) . for the above reaction, K_(p) is 4, K_c will be

RESONANCE ENGLISH-RANK BOOSTER-All Questions
  1. Statement-1 :Graphite can be converted into diamond by application of ...

    Text Solution

    |

  2. How many moles of potassium chlorate need to be heated to produce 5.2 ...

    Text Solution

    |

  3. Assertion : Ag(2) S + 4 KCN hArr 2K [Ag(CN)(2)] + K(2) S Reason : Th...

    Text Solution

    |

  4. A gas 'X' when dissolved in water, heat is evolved. Then solubility of...

    Text Solution

    |

  5. Au(s)hArrAu(l) The formation of liquid is favoured at

    Text Solution

    |

  6. For the reaction 1/2N2(g)+1/2O2(g)hArrNO(g). If pressure is increased ...

    Text Solution

    |

  7. The plot of log K against 1/T is a straight line with positive slope (...

    Text Solution

    |

  8. A sample of mixture of A(g),B(g) and C(g) under equilibrium has a mean...

    Text Solution

    |

  9. What mass of potassium chlorate (KClO3) on heating gives 1.591 g of po...

    Text Solution

    |

  10. The KP for the reaction N2O4 hArr 2NO2 is 640 mm at 775 K.The percenta...

    Text Solution

    |

  11. Fe has been placed in the eighth group, the number of electrons in the...

    Text Solution

    |

  12. The equation alpha=(D-d)/((n-1)d) is correctly matched for :

    Text Solution

    |

  13. The number of incomplete orbits in inner transition elements is

    Text Solution

    |

  14. The number of unpaired electrons in Zn element is

    Text Solution

    |

  15. State true or false : 3d^0 4s^0 electronic configuration exhibit...

    Text Solution

    |

  16. Match the following : {:("Reaction (Homogeneous gaseous phase)","D...

    Text Solution

    |

  17. NH(3) is heated at 15 atm, from 25^(@)C to 347^(@)C assuming volume co...

    Text Solution

    |

  18. The equilibrium constant for the reaction Br2(l)+Cl(2)(g)hArr2Br Cl(g)...

    Text Solution

    |

  19. Following two equilibria are established on mixing two gases A(2) and ...

    Text Solution

    |

  20. Two solids AB and CB2 are simultaneously heated in a closed vessel to ...

    Text Solution

    |