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Match the following : {:("Reaction (...

Match the following :
`{:("Reaction (Homogeneous gaseous phase)","Degree of dissociation in terms of equilibrium constant"),((A)A(g)+B(g)hArr2C(g),(p)(sqrtk)//(1+sqrtk)),((B)2A(g)hArr+B(g)+C(g),(q)(sqrtk)//(2+sqrtk)),((C )A(g)+B(g)hArrC(g)+D(g),(r)2k//(1+2k)),((D)AB(g)hArrA/2(g)+B/2(g),(s)(2sqrtk)/(1+2sqrtk)),(,(t)k):}`

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To solve the problem of matching the reactions with their corresponding degree of dissociation in terms of equilibrium constant, we will analyze each reaction step by step. ### Step 1: Analyze Reaction A **Reaction:** A(g) + B(g) ⇌ 2C(g) 1. **Initial Concentrations:** - [A] = C₀ - [B] = C₀ - [C] = 0 2. **At Equilibrium:** - [A] = C₀(1 - α) - [B] = C₀(1 - α) - [C] = 2C₀α 3. **Equilibrium Constant (K):** \[ K = \frac{[C]^2}{[A][B]} = \frac{(2C₀α)^2}{C₀(1 - α)C₀(1 - α)} = \frac{4C₀^2α^2}{C₀^2(1 - α)^2} \] Simplifying gives: \[ K = \frac{4α^2}{(1 - α)^2} \] 4. **Expressing α in terms of K:** \[ 2α = \sqrt{K}(1 - α) \implies 2α + α\sqrt{K} = \sqrt{K} \implies α(2 + \sqrt{K}) = \sqrt{K} \] \[ α = \frac{\sqrt{K}}{2 + \sqrt{K}} \] **Match:** Reaction A matches with (q) \(\frac{\sqrt{K}}{2 + \sqrt{K}}\). ### Step 2: Analyze Reaction B **Reaction:** 2A(g) ⇌ B(g) + C(g) 1. **Initial Concentrations:** - [A] = C₀ - [B] = 0 - [C] = 0 2. **At Equilibrium:** - [A] = C₀(1 - 2α) - [B] = C₀α - [C] = C₀α 3. **Equilibrium Constant (K):** \[ K = \frac{[B][C]}{[A]^2} = \frac{C₀α \cdot C₀α}{(C₀(1 - 2α))^2} = \frac{C₀^2α^2}{C₀^2(1 - 2α)^2} \] Simplifying gives: \[ K = \frac{α^2}{(1 - 2α)^2} \] 4. **Expressing α in terms of K:** \[ \sqrt{K} = \frac{α}{1 - 2α} \implies α = \sqrt{K}(1 - 2α) \implies α + 2α\sqrt{K} = \sqrt{K} \] \[ α(1 + 2\sqrt{K}) = \sqrt{K} \implies α = \frac{\sqrt{K}}{1 + 2\sqrt{K}} \] **Match:** Reaction B matches with (s) \(\frac{2\sqrt{K}}{1 + 2\sqrt{K}}\). ### Step 3: Analyze Reaction C **Reaction:** A(g) + B(g) ⇌ C(g) + D(g) 1. **Initial Concentrations:** - [A] = C₀ - [B] = C₀ - [C] = 0 - [D] = 0 2. **At Equilibrium:** - [A] = C₀(1 - α) - [B] = C₀(1 - α) - [C] = C₀α - [D] = C₀α 3. **Equilibrium Constant (K):** \[ K = \frac{[C][D]}{[A][B]} = \frac{C₀α \cdot C₀α}{C₀(1 - α)C₀(1 - α)} = \frac{α^2}{(1 - α)^2} \] 4. **Expressing α in terms of K:** \[ \sqrt{K} = \frac{α}{1 - α} \implies α = \sqrt{K}(1 - α) \implies α + α\sqrt{K} = \sqrt{K} \] \[ α(1 + \sqrt{K}) = \sqrt{K} \implies α = \frac{\sqrt{K}}{1 + \sqrt{K}} \] **Match:** Reaction C matches with (p) \(\frac{α}{1 + α}\). ### Step 4: Analyze Reaction D **Reaction:** AB(g) ⇌ A/2(g) + B/2(g) 1. **Initial Concentrations:** - [AB] = C₀ - [A] = 0 - [B] = 0 2. **At Equilibrium:** - [AB] = C₀(1 - α) - [A] = C₀α/2 - [B] = C₀α/2 3. **Equilibrium Constant (K):** \[ K = \frac{[A/2][B/2]}{[AB]} = \frac{(C₀α/2)(C₀α/2)}{C₀(1 - α)} = \frac{C₀^2α^2/4}{C₀(1 - α)} = \frac{C₀α^2}{4(1 - α)} \] 4. **Expressing α in terms of K:** \[ K = \frac{α^2}{4(1 - α)} \implies 4K(1 - α) = α^2 \implies α^2 + 4Kα - 4K = 0 \] Using the quadratic formula: \[ α = \frac{-4K \pm \sqrt{(4K)^2 + 16K}}{2} = \frac{-4K \pm 4\sqrt{K}}{2} \] Simplifying gives: \[ α = \frac{2\sqrt{K}}{1 + 2K} \] **Match:** Reaction D matches with (r) \(\frac{2K}{1 + 2K}\). ### Final Matches: - A matches with (q) - B matches with (s) - C matches with (p) - D matches with (r)

To solve the problem of matching the reactions with their corresponding degree of dissociation in terms of equilibrium constant, we will analyze each reaction step by step. ### Step 1: Analyze Reaction A **Reaction:** A(g) + B(g) ⇌ 2C(g) 1. **Initial Concentrations:** - [A] = C₀ - [B] = C₀ ...
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