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If the wave number of 1^(st) line of Bal...

If the wave number of `1^(st)` line of Balmer series of H-atom is 'x' then :

A

Wave number of `1^(st)` line of lyman series of the `He^(+)` ion will be `(108 x)/5`

B

Wave number of `1^(st)` line of lyman series of the `He^(+)` ion will be `(36x)/5`

C

The wave length of `2^(nd)` line of lyman series of H-atom is `5/(32x)`

D

The wave length of `2^(nd)` line of lyman series of H-atom is `(32x)/5`

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To solve the problem regarding the wave number of the first line of the Balmer series of the hydrogen atom, we will follow these steps: ### Step 1: Understand the Formula The wave number \( \bar{v} \) (in cm\(^{-1}\)) for the transition between energy levels in a hydrogen atom can be calculated using the formula: \[ \bar{v} = RZ^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where: - \( R \) is the Rydberg constant (\( R \approx 1.097 \times 10^7 \, \text{m}^{-1} \)), - \( Z \) is the atomic number (for hydrogen, \( Z = 1 \)), - \( n_1 \) and \( n_2 \) are the principal quantum numbers of the lower and higher energy levels, respectively. ### Step 2: Identify the Transition for the First Line of the Balmer Series For the first line of the Balmer series, the transition occurs from \( n_2 = 3 \) to \( n_1 = 2 \). ### Step 3: Calculate the Wave Number Substituting the values into the formula: \[ \bar{v} = R \left( \frac{1}{2^2} - \frac{1}{3^2} \right) = R \left( \frac{1}{4} - \frac{1}{9} \right) \] Calculating the fractions: \[ \frac{1}{4} - \frac{1}{9} = \frac{9 - 4}{36} = \frac{5}{36} \] Thus, we have: \[ \bar{v} = R \cdot \frac{5}{36} \] ### Step 4: Relate to Given Wave Number \( x \) We are given that the wave number of the first line of the Balmer series is \( x \). Therefore, we can express \( x \) as: \[ x = R \cdot \frac{5}{36} \] ### Step 5: Determine the Wave Number for the First Line of the Lyman Series For the first line of the Lyman series, the transition is from \( n_2 = 2 \) to \( n_1 = 1 \): \[ \bar{v}_{Lyman} = R \left( \frac{1}{1^2} - \frac{1}{2^2} \right) = R \left( 1 - \frac{1}{4} \right) = R \cdot \frac{3}{4} \] Now, we can express this in terms of \( x \): \[ \bar{v}_{Lyman} = R \cdot \frac{3}{4} = \frac{3}{4} \cdot \frac{36}{5} x = \frac{27}{5} x \] ### Step 6: Determine the Wavelength of the Second Line of the Lyman Series The second line of the Lyman series corresponds to a transition from \( n_2 = 3 \) to \( n_1 = 1 \): \[ \bar{v}_{Lyman, 2} = R \left( 1 - \frac{1}{3^2} \right) = R \left( 1 - \frac{1}{9} \right) = R \cdot \frac{8}{9} \] Expressing this in terms of \( x \): \[ \bar{v}_{Lyman, 2} = R \cdot \frac{8}{9} = \frac{8}{9} \cdot \frac{36}{5} x = \frac{64}{45} x \] ### Step 7: Find the Wavelength The wavelength \( \lambda \) is the inverse of the wave number: \[ \lambda = \frac{1}{\bar{v}} = \frac{1}{\frac{64}{45} x} = \frac{45}{64 x} \] ### Conclusion Based on the calculations, we can summarize the results: - The wave number of the first line of the Lyman series of helium plus is \( \frac{108}{5} x \). - The wavelength of the second line of the Lyman series of hydrogen atom is \( \frac{45}{64} x \).

To solve the problem regarding the wave number of the first line of the Balmer series of the hydrogen atom, we will follow these steps: ### Step 1: Understand the Formula The wave number \( \bar{v} \) (in cm\(^{-1}\)) for the transition between energy levels in a hydrogen atom can be calculated using the formula: \[ \bar{v} = RZ^2 \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right) \] where: ...
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