Home
Class 12
CHEMISTRY
Statement-1 : The 5^(th) period of perio...

Statement-1 : The `5^(th)` period of periodic table contains 18 elements not 32.
Statement-2 : n=5,l=0,1,2,3. The order in which the energy of available orbitals 4d, 5s, 5p increases is `5slt4dlt5p` and the total number of orbitals available are 9 and thus 18 electrons can be accomodated.

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1

C

Statement-1 is True, Statement-2 is False.

D

Statement-1 is False, Statement-2 is True.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both statements provided and verify their correctness. ### Step 1: Analyze Statement 1 **Statement 1:** The 5th period of the periodic table contains 18 elements, not 32. - The 5th period corresponds to the principal quantum number \( n = 5 \). - In the 5th period, the following orbitals are filled: - \( 5s \) (1 orbital) - \( 4d \) (5 orbitals) - \( 5p \) (3 orbitals) **Calculation of total orbitals:** - Total orbitals = 1 (from \( 5s \)) + 5 (from \( 4d \)) + 3 (from \( 5p \)) = 9 orbitals. **Calculation of total electrons:** - Each orbital can hold a maximum of 2 electrons. - Therefore, total electrons = \( 9 \text{ orbitals} \times 2 \text{ electrons/orbital} = 18 \text{ electrons} \). Thus, the 5th period contains 18 elements, confirming that Statement 1 is **correct**. ### Step 2: Analyze Statement 2 **Statement 2:** The order in which the energy of available orbitals \( 4d, 5s, 5p \) increases is \( 5s < 4d < 5p \). - According to the \( n + l \) rule: - For \( 5s \): \( n + l = 5 + 0 = 5 \) - For \( 4d \): \( n + l = 4 + 2 = 6 \) - For \( 5p \): \( n + l = 5 + 1 = 6 \) Since both \( 4d \) and \( 5p \) have the same \( n + l \) value, we compare their \( n \) values: - \( 5s \) has the lowest energy, followed by \( 4d \) and then \( 5p \). Thus, the correct order of increasing energy is indeed \( 5s < 4d < 5p \), confirming that Statement 2 is also **correct**. ### Step 3: Conclusion Both statements are correct, and Statement 2 provides a correct explanation for Statement 1. ### Final Answer The answer to the question is: **Both statements are true, and Statement 2 is a correct explanation of Statement 1.** ---

To solve the question, we need to analyze both statements provided and verify their correctness. ### Step 1: Analyze Statement 1 **Statement 1:** The 5th period of the periodic table contains 18 elements, not 32. - The 5th period corresponds to the principal quantum number \( n = 5 \). - In the 5th period, the following orbitals are filled: - \( 5s \) (1 orbital) ...
Promotional Banner

Topper's Solved these Questions

  • QUALITATIVE ANALYSIS PART 1

    RESONANCE ENGLISH|Exercise A.L.P|39 Videos
  • SOLID STATE

    RESONANCE ENGLISH|Exercise PHYSICAL CHEMITRY (SOLID STATE)|45 Videos

Similar Questions

Explore conceptually related problems

Which block of the periodic table contains the element with configuration 1s^2 2s^2 2p^6 3s^2 3p^6 3d^(10) 4s^1

Total number of elements of 5th period which have one or more than one 5d electrons :-

Statement-1 :Xenon forms fluorides. Statement-2 :5 d-orbitals are available in xenon for valence shell expansion.

Statement-I : The ground state configuration of Cr is 3d^(5) 4s^(1) . Because Statement-II : A set of exactly half filled orbitals containing parallel spin arrangement provide extra stability.

Statement-I : The ground state configuration of Cr is 3d^(5) 4s^(1) . Because Statement-II : A set of exactly half filled orbitals containing parallel spin arrangement provide extra stability.

4d, 5p, 5f and 6p orbitals are arranged in the order of decreasing energy. The correct option is :

Statement-1 : The groundstate configuration of Cr is [Ar] 3d^(5) 4s^(1) Statement-2 : The energy of atom is lesser in 3d^(5)4s^(1) configuration compared to 3d^(4)4s^(2) configuration.

Arrange the following orbital in the increasing order of the energy 3s, 4d, 2p, 4s,3p

Arrange the following orbital in the increasing order of the energy 3s, 4d, 2p, 4s,3p

STATEMENT-1 : The 19^(th) electron in potassium atom enters into 4s-orbital than in 3d-orbital. and STATEMENT-2 : (n+1l) rule is followed for determining the orbital of lowest energy state.

RESONANCE ENGLISH-RANK BOOSTER-All Questions
  1. John Newland arranged the element starting with hydrogen and ending wi...

    Text Solution

    |

  2. Select the incorrect statement(s).

    Text Solution

    |

  3. Statement-1 : The 5^(th) period of periodic table contains 18 elements...

    Text Solution

    |

  4. (Cu, Ag, Au) does not follow Dobereiner's law of triads,why?

    Text Solution

    |

  5. Statement-1: Third ionisation energy of phosphorous is larger than sul...

    Text Solution

    |

  6. Statement-1:Manganese (atomic number 25) has a less favourable electro...

    Text Solution

    |

  7. Assertion: Electron gain enthalpy always becomes less negative as we g...

    Text Solution

    |

  8. the group which has maximum number of element in Mendeleev's periodic ...

    Text Solution

    |

  9. Who classified the elements on the basis of fundamental properties of ...

    Text Solution

    |

  10. The periodicity is related to the electronic configuration. That is, a...

    Text Solution

    |

  11. Which element reacts most explosively in water? Li or K

    Text Solution

    |

  12. The elements of group 1 describe, more clearly than any other group of...

    Text Solution

    |

  13. 150 mL of pure phosphine is decomposed to produce vapours of phosphoru...

    Text Solution

    |

  14. The first (Delta(i), H(1)) and the second (Delta, H(2)) ionisation ent...

    Text Solution

    |

  15. The first (DeltaiH1) and the second (DeltaiH2) ionization enthalpies (...

    Text Solution

    |

  16. The first (DeltaiH1) and the second (DeltaiH2) ionization enthalpies (...

    Text Solution

    |

  17. The amount of energy released when an atom in the gaseous state accep...

    Text Solution

    |

  18. Which one of the following statements is incorrect in relation to ioni...

    Text Solution

    |

  19. Considering the elements F, Cl, O and N, the correct order of their ch...

    Text Solution

    |

  20. 18 g of sodium chloride is dissolved in 100 g of water at 293 K. Find ...

    Text Solution

    |