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The periodicity is related to the electr...

The periodicity is related to the electronic configuration. That is, all chemical and phyical properties are a manifestation of the electronic configurfation of the elements.
The atomic and ionic radii generally decrease in a preiod from left or right. As a consequence , the ionisation enthalpies generally increase and electron gain enthalpies become more negative across a period. In other words, the ionisation enthalpy of the extreme left element in a period is the least and the electron left element on the extreme right is the highest negative. This results into high chemical reactivity at two extgremes and the lowest in the centre. Similarly down the group, the increase in atomic and ionic radii result in gradual decrease (with excetption in some third period elements) in electron gain enthalpies in the case of main group elements .
These properties can be related with the
(i) reducing and oxidising behacviour of the elements
(ii) metallic and no-metallic charcter of element
(iii) acidic, basic , amphoteric and neutral character of the oxides of the elements.
Among `Al_(2)O_(3), SiO_(2),P_(2)O_(3)` and `SO_(2)` the correct order of acid strenght is :

A

`Al_2O_3lt SiO_2ltSO_2lt P_2O_3`

B

`SiO_2ltSO_2ltAl_2O_3ltP_2O_3`

C

`SO_2ltP_2O_3ltSiO_2ltAl_2O_3`

D

`Al_2O_3ltSiO_2ltP_2O_3ltSO_2`

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The correct Answer is:
To determine the correct order of acidic strength among the oxides \( Al_2O_3 \), \( SiO_2 \), \( P_2O_3 \), and \( SO_2 \), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Elements and Their Positions in the Periodic Table:** - Aluminum (Al) is a group 13 element. - Silicon (Si) is a group 14 element. - Phosphorus (P) is a group 15 element. - Sulfur (S) is a group 16 element. 2. **Understand the Nature of the Oxides:** - Metal oxides (like \( Al_2O_3 \)) tend to be basic. - Non-metal oxides (like \( SiO_2 \), \( P_2O_3 \), and \( SO_2 \)) tend to be acidic. 3. **Analyze the Acidic Strength Based on Non-metallic Character:** - As we move from left to right across a period, the non-metallic character increases, which correlates with an increase in acidic behavior of the oxides. - Therefore, we can expect the acidic strength to increase from \( Al_2O_3 \) to \( SO_2 \). 4. **Order the Oxides Based on Acidic Strength:** - \( Al_2O_3 \) (least acidic, basic oxide) - \( SiO_2 \) (weakly acidic) - \( P_2O_3 \) (more acidic than \( SiO_2 \)) - \( SO_2 \) (most acidic) 5. **Final Order of Acidic Strength:** - The correct order of acidic strength is: \[ Al_2O_3 < SiO_2 < P_2O_3 < SO_2 \]

To determine the correct order of acidic strength among the oxides \( Al_2O_3 \), \( SiO_2 \), \( P_2O_3 \), and \( SO_2 \), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Elements and Their Positions in the Periodic Table:** - Aluminum (Al) is a group 13 element. - Silicon (Si) is a group 14 element. - Phosphorus (P) is a group 15 element. ...
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Ionisation Enthalpy

The periodicity is related to the electronic configuration. That is, all chemical and physical properties are a manifestation of the electronic configuration of the elements. The atomic and ionic radii generally decrease in a period from left to right. As a consequence, the ionization enthalpies generally increase and electron gain enthalpies become more negative across a period. In other words, the ionization enthalpy of the exterme left element in a period is the least and teh electron gain enthalpy of the element on the exterme right is the highest negative. This results into high chemical reactivity at the two extermes and the lowest in he centre. Similarly down the group, the increase in atomic and ionic radii result in gradual decrease in ionization enthalpies and a regular decrease (with exception in some third period elements) in electron gain enthalpies in the case of main group elements. The loss and gain of electrons can be co-related with the reducting and oxidising behaviour, and also with metallic and non-metallic character respectively, of the elements. The correct order of the metallic character is:

The periodicity is related to the electronic configuration. That is, all chemical and physical properties are a manifestation of the electronic configuration of the elements. The atomic and ionic radii generally decrease in a period from left to right. As a consequence, the ionization enthalpies generally increase and electron gain enthalpies become more negative across a period. In other words, the ionization enthalpy of the exterme left element in a period is the least and teh electron gain enthalpy of the element on the exterme right is the highest negative. This results into high chemical reactivity at the two extermes and the lowest in he centre. Similarly down the group, the increase in atomic and ionic radii result in gradual decrease in ionization enthalpies and a regular decrease (with exception in some third period elements) in electron gain enthalpies in the case of main group elements. The loss and gain of electrons can be co-related with the reducting and oxidising behaviour, and also with metallic and non-metallic character respectively, of the elements. Which of the following statements is correct?

The periodicity is related to the electronic configuration. That is, all chemical and physical properties are a manifestation of the electronic configuration of the elements. The atomic and ionic radii generally decrease in a period from left to right. As a consequence, the ionization enthalpies generally increase and electron gain enthalpies become more negative across a period. In other words, the ionization enthalpy of the exterme left element in a period is the least and teh electron gain enthalpy of the element on the exterme right is the highest negative. This results into high chemical reactivity at the two extermes and the lowest in he centre. Similarly down the group, the increase in atomic and ionic radii result in gradual decrease in ionization enthalpies and a regular decrease (with exception in some third period elements) in electron gain enthalpies in the case of main group elements. The loss and gain of electrons can be co-related with the reducting and oxidising behaviour, and also with metallic and non-metallic character respectively, of the elements. Considering the elements B, C, N, F and Si , the correct order of their non-metallic character is:

Electron gain enthalpies of noble gases are negative.

The element with positive electron gain enthalpy is

In Group 18, the element with highest electron gain enthalpy is

Match the correct ionisation enthalpies and electron gain enthalpies of the following elements.

With which of the following electronic configuration of an atom has the lowest ionization enthalpy:

The trend in ionisation enthalpy of transition element is not regular because

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