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Select the correct statement(s) with res...

Select the correct statement(s) with respect to the `p pi-dpi` dative bond.

A

In `(Ph_3Si)_2O`, the Si-O-Si group is nearly linear

B

Silanols such as `(CH_3)_3` SiOH are stronger protonic acids then their carbon analogs

C

Trisilysl phosphine `(H_3Si)_3` P is planar

D

`CIO_4^-` does not polymerise at all

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The correct Answer is:
To solve the question regarding the correct statements about the `p pi-d pi` dative bond, we will analyze each statement provided in the question step by step. ### Step-by-Step Solution: 1. **Statement 1: In Ph3Si2O, the Si-O-Si group is nearly linear.** - **Analysis**: The presence of bulky phenyl groups creates steric hindrance, which favors a linear arrangement for the Si-O-Si group. Additionally, the p-pi-d-pi bonding contributes to this linearity. - **Conclusion**: This statement is **correct**. 2. **Statement 2: Silanols such as CH3-3SiOH are stronger protonic acids than their carbon analogs.** - **Analysis**: Silanols can donate protons (H+) easily due to the stability of the resulting anion (CH3)3SiO-. This stability arises from the p-pi-d-pi bonding between the p orbital of oxygen and the d orbital of silicon. Carbon analogs lack d orbitals, which makes them less capable of stabilizing the anion formed after proton donation. - **Conclusion**: This statement is **correct**. 3. **Statement 3: Trisilylphosphine is planar.** - **Analysis**: Trisilylphosphine does not exhibit planarity because the d-pi-pi bonding is not effective due to the larger size of phosphorus. The larger atomic size prevents effective overlap necessary for planar structures. - **Conclusion**: This statement is **incorrect**. 4. **Statement 4: ClO4- does not polymerize at all.** - **Analysis**: The ClO4- ion is stable and exists as a monomer due to the effective d-pi-pi bonding, which is facilitated by the small size of chlorine. This prevents polymerization. - **Conclusion**: This statement is **correct**. ### Final Conclusion: The correct statements regarding the `p pi-d pi` dative bond are: - Statement 1: Correct - Statement 2: Correct - Statement 3: Incorrect - Statement 4: Correct Thus, the correct statements are **1, 2, and 4**.

To solve the question regarding the correct statements about the `p pi-d pi` dative bond, we will analyze each statement provided in the question step by step. ### Step-by-Step Solution: 1. **Statement 1: In Ph3Si2O, the Si-O-Si group is nearly linear.** - **Analysis**: The presence of bulky phenyl groups creates steric hindrance, which favors a linear arrangement for the Si-O-Si group. Additionally, the p-pi-d-pi bonding contributes to this linearity. - **Conclusion**: This statement is **correct**. ...
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