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Assertion Bond order in a molecule can a...

Assertion Bond order in a molecule can assume any integral value or fractional value including zero
Reasoning It depends on number of electrons in the bonding and antibonding orbitals .

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1

C

Statement-1 is True, Statement-2 is False.

D

Statement-1 is False, Statement-2 is True.

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The correct Answer is:
To solve the question, we need to analyze both the assertion and the reasoning provided. ### Step 1: Understanding the Assertion The assertion states that "Bond order in a molecule can assume any integral value or fractional value including zero." - **Bond Order Definition**: Bond order is defined as the difference between the number of bonding electrons and the number of antibonding electrons, divided by 2. \[ \text{Bond Order} = \frac{(\text{Number of bonding electrons} - \text{Number of antibonding electrons})}{2} \] ### Step 2: Evaluating the Assertion - The bond order can indeed take fractional values (like 1.5) and integral values (like 1, 2, etc.). - However, the bond order cannot be negative or less than zero because the number of antibonding electrons cannot exceed the number of bonding electrons in a stable molecule. Thus, the assertion is **false** because it incorrectly includes zero as a possible bond order. ### Step 3: Understanding the Reasoning The reasoning states that "It depends on the number of electrons in the bonding and antibonding orbitals." - This statement is true. The bond order is directly calculated based on the number of electrons in bonding and antibonding orbitals. ### Step 4: Evaluating the Reasoning - Since the bond order is calculated using the formula mentioned, the reasoning is indeed correct. It accurately describes how bond order is determined. ### Conclusion - The assertion is **false** because bond order cannot be zero or negative. - The reasoning is **true** because it correctly explains the dependence of bond order on the number of bonding and antibonding electrons. ### Final Answer - The assertion is false, and the reasoning is true. Therefore, the correct option is that the assertion is false, and the reasoning is true.

To solve the question, we need to analyze both the assertion and the reasoning provided. ### Step 1: Understanding the Assertion The assertion states that "Bond order in a molecule can assume any integral value or fractional value including zero." - **Bond Order Definition**: Bond order is defined as the difference between the number of bonding electrons and the number of antibonding electrons, divided by 2. \[ ...
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