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In the valence bond theory, hybridisatio...

In the valence bond theory, hybridisation of orbitals is an integral part of bond formation.Hybridisation consists of mixing or linear combination of the "pure" atomic orbitals in such a way as to form new hybrid orbitals such as `sp, sp^2, sp^3, sp^3d , sp^3d^2` etc.
Now answer the following questions :
Which of the following are isostructural ?
`{:(NO_3^(-),CO_3^(2-),CIO_3^(-),SO_3,XeO_3),((I),(II),(III),(IV),"(V)"):}`

A

(I) and (IV)

B

(II) and (V)

C

(III) and (IV)

D

(IV) and (V)

Text Solution

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The correct Answer is:
A

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In the valence bond theory, hybridisation of orbitals is an integral part of bond formation.Hybridisation consists of mixing or linear combination of the "pure" atomic orbitals in such a way as to form new hybrid orbitals such as sp, sp^2, sp^3, sp^3d , sp^3d^2 etc. Now answer the following questions : Which one of the following molecular geometrices (i.e. shapes) is not possible for the sp^3d^3 hybridisation ?

In the valence bond theory, hybridisation of orbitals is an integral part of bond formation.Hybridisation consists of mixing or linear combination of the "pure" atomic orbitals in such a way as to form new hybrid orbitals such as sp, sp^2, sp^3, sp^3d , sp^3d^2 etc. Now answer the following questions : Which of the following atomic orbitals does not participitate in trigonal bipyramidal hybridisation i.e. sp^3d hybridisation ?

Sp^3d Hybridisation

Which of the following have sp^(3) d hybridisation ? .

An sp^(3) hybrid orbital possesses

What is meant by hybridisation of atomic orbitals? Describe the shapes of sp, sp^2, sp^3 hybrid orbitals.

In which reaction, the hybridisation on the central atom changes from sp^(2) to sp^(3) .

A molecule is formed by sp^3d^2 hybridisation. Bond angle in it is :

How much s and p characters are present in sp^3 hybrid orbitals?

The ion that has sp ^ 3 d ^ 2 hybridization for the central atom, is :

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