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The possible geometric isomers of the co...

The possible geometric isomers of the complex , `[Co(en) Br_2Cl_2]^(-)` is :

A

2

B

3

C

4

D

6

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The correct Answer is:
To determine the possible geometric isomers of the complex \([Co(en)Br_2Cl_2]^-\), we need to analyze the coordination geometry and the ligands involved. ### Step-by-Step Solution: 1. **Identify the Coordination Number and Geometry**: - The cobalt complex has a coordination number of 6 due to the presence of two bidentate ligands (ethylenediamine, en) and four monodentate ligands (two bromides and two chlorides). - The geometry of a coordination complex with a coordination number of 6 is octahedral. 2. **Identify the Ligands**: - The ligands in the complex are: - Ethylenediamine (en) - a bidentate ligand that occupies two coordination sites. - Two bromide ions (Br) - monodentate ligands. - Two chloride ions (Cl) - monodentate ligands. 3. **Determine Possible Arrangements**: - Since en is a bidentate ligand, it will occupy two adjacent positions in the octahedral geometry. The remaining four positions will be occupied by the two bromides and two chlorides. - The geometric isomers can be categorized based on the relative positions of the bromides and chlorides. 4. **Construct the Isomers**: - **Isomer 1**: Place the two bromides trans to each other and the two chlorides trans to each other. - **Isomer 2**: Place the two chlorides trans to each other and the two bromides trans to each other. - **Isomer 3**: Place one bromide and one chloride adjacent to each other, and the other bromide and chloride adjacent to each other. - **Isomer 4**: Place the two bromides adjacent to each other and the two chlorides adjacent to each other. 5. **Count the Isomers**: - After constructing the arrangements, we find that there are a total of 4 distinct geometric isomers. ### Final Answer: The possible geometric isomers of the complex \([Co(en)Br_2Cl_2]^-\) are **4**.

To determine the possible geometric isomers of the complex \([Co(en)Br_2Cl_2]^-\), we need to analyze the coordination geometry and the ligands involved. ### Step-by-Step Solution: 1. **Identify the Coordination Number and Geometry**: - The cobalt complex has a coordination number of 6 due to the presence of two bidentate ligands (ethylenediamine, en) and four monodentate ligands (two bromides and two chlorides). - The geometry of a coordination complex with a coordination number of 6 is octahedral. ...
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