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Statement-1:In natural tris chelating co...

Statement-1:In natural tris chelating complex, `[Co(acac)_3]`, in each ring the two `M-O` bonds are equal in length, as are two C-O and the two C-C bonds because.
Statement-2:In each ring resonance take place.

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1

C

Statement-1 is True, Statement-2 is False.

D

Statement-1 is False, Statement-2 is True.

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The correct Answer is:
To solve the question, we will analyze both statements and provide a step-by-step explanation. ### Step 1: Understanding the Complex We are given the complex `[Co(acac)3]`, where `acac` stands for acetylacetone. This complex has a tris-chelating structure, meaning that three acetylacetone ligands are coordinated to the cobalt ion. ### Step 2: Drawing the Structure To visualize the complex, we can draw the structure of one of the acetylacetone ligands. Each ligand forms a five-membered chelate ring with the cobalt ion. The structure can be represented as follows: - Each acetylacetone ligand has two oxygen atoms (O) that coordinate to the cobalt (Co) and form a ring structure with carbon (C) atoms. ### Step 3: Analyzing Bond Lengths In the rings formed by the acetylacetone ligands: - The two `M-O` (metal-oxygen) bonds are equivalent in length due to the symmetrical nature of the chelate ring. - Similarly, the two `C-O` (carbon-oxygen) bonds and the two `C-C` (carbon-carbon) bonds are also equal in length. ### Step 4: Understanding Resonance The reason for the equality of bond lengths in the rings is due to resonance. In each ring: - The double bonds can shift, allowing for the delocalization of electrons across the ring structure. - This delocalization leads to an equal distribution of electron density, resulting in equal bond lengths. ### Step 5: Evaluating the Statements - **Statement 1**: This statement is true because the bond lengths in the rings are indeed equal. - **Statement 2**: This statement is also true as resonance occurs in the rings, which explains why the bond lengths are equal. ### Step 6: Conclusion Since both statements are true and Statement 2 correctly explains Statement 1, we conclude that the answer is that both statements are true, and Statement 2 is the correct explanation for Statement 1. ### Final Answer Both Statement 1 and Statement 2 are true, and Statement 2 is the correct explanation for Statement 1. ---

To solve the question, we will analyze both statements and provide a step-by-step explanation. ### Step 1: Understanding the Complex We are given the complex `[Co(acac)3]`, where `acac` stands for acetylacetone. This complex has a tris-chelating structure, meaning that three acetylacetone ligands are coordinated to the cobalt ion. ### Step 2: Drawing the Structure To visualize the complex, we can draw the structure of one of the acetylacetone ligands. Each ligand forms a five-membered chelate ring with the cobalt ion. The structure can be represented as follows: ...
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