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The question consist of two statements e...

The question consist of two statements each, printed as Assertion and Reason. While answering these questions you are required to choose any one of the following four responses:
Assertion: Co-ordination number of cobalt in the complex `[Co(en)_3]^(3+)` is six.
Reason: Ethylenediamine acts as a bidentate ligand.

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1

C

Statement-1 is True, Statement-2 is False.

D

Statement-1 is False, Statement-2 is True.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we will analyze both the Assertion and the Reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the coordination number of cobalt in the complex \([Co(en)_3]^{3+}\) is six. - The coordination number is defined as the number of ligand atoms that are bonded to the central metal ion. 2. **Analyzing the Ligand**: - The ligand in question is ethylenediamine (en), which is a bidentate ligand. - A bidentate ligand can attach to a metal ion at two points, meaning it can form two bonds with the metal. 3. **Counting the Ligands**: - In the complex \([Co(en)_3]^{3+}\), there are three ethylenediamine ligands. - Since each ethylenediamine ligand can form two bonds with the cobalt ion, the total number of bonds formed is: \[ 3 \text{ (ligands)} \times 2 \text{ (bonds per ligand)} = 6 \text{ bonds} \] - Therefore, the coordination number of cobalt in this complex is indeed 6. 4. **Understanding the Reason**: - The reason states that ethylenediamine acts as a bidentate ligand. - This is a correct statement because ethylenediamine has two nitrogen atoms that can donate lone pairs to the metal ion, allowing it to bind at two sites. 5. **Conclusion**: - Both the assertion and the reason are true. - Furthermore, the reason provides a correct explanation for the assertion, as it describes how ethylenediamine contributes to the coordination number of cobalt. ### Final Answer: - The correct response is: - Both the assertion and the reason are true, and the reason is the correct explanation of the assertion.

To solve the question, we will analyze both the Assertion and the Reason provided. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the coordination number of cobalt in the complex \([Co(en)_3]^{3+}\) is six. - The coordination number is defined as the number of ligand atoms that are bonded to the central metal ion. ...
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