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The question consist of two statements e...

The question consist of two statements each, printed as Assertion and Reason. While answering these questions you are required to choose any one of the following four responses:
Assertion: Charge on the complex of ferric ion with EDTA is minus one.
Reason: EDTA is a hexadentate ligand.

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1

C

Statement-1 is True, Statement-2 is False.

D

Statement-1 is False, Statement-2 is True.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the assertion and reason statements, we will analyze both the assertion and the reason step by step. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the charge on the complex of the ferric ion (Fe³⁺) with EDTA is -1. - To evaluate this, we need to know the charge of the ferric ion and the charge of the EDTA ligand. 2. **Charge of Ferric Ion**: - The ferric ion (Fe³⁺) has a charge of +3. 3. **Understanding EDTA**: - EDTA (ethylenediaminetetraacetic acid) is a hexadentate ligand, meaning it can form six bonds with a metal ion. - The overall charge of the EDTA ligand is -4 because it can donate four acetate groups (each contributing -1 charge) and two nitrogen atoms (which do not contribute to the charge). 4. **Calculating the Charge of the Complex**: - When the ferric ion (Fe³⁺) binds with EDTA (EDTA⁴⁻), the overall charge of the complex can be calculated as follows: \[ \text{Charge of complex} = \text{Charge of Fe} + \text{Charge of EDTA} = (+3) + (-4) = -1 \] - Therefore, the assertion that the charge on the complex is -1 is correct. 5. **Understanding the Reason**: - The reason states that EDTA is a hexadentate ligand. - This is also true, as EDTA can indeed bind to a metal ion at six coordination sites. 6. **Evaluating the Relationship Between Assertion and Reason**: - While both the assertion and the reason are true, the reason does not explain why the charge of the complex is -1. The charge calculation is based on the specific charges of the ferric ion and the EDTA ligand, not solely on the fact that EDTA is hexadentate. ### Conclusion: - Both the assertion and the reason are true, but the reason is not the correct explanation for the assertion. Therefore, the correct response is: **Assertion is true, Reason is true, but Reason is not the correct explanation of Assertion.**

To solve the question regarding the assertion and reason statements, we will analyze both the assertion and the reason step by step. ### Step-by-Step Solution: 1. **Understanding the Assertion**: - The assertion states that the charge on the complex of the ferric ion (Fe³⁺) with EDTA is -1. - To evaluate this, we need to know the charge of the ferric ion and the charge of the EDTA ligand. ...
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