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{:("Column-I","Column-II"),((A)[Ni(CO)4]...

`{:("Column-I","Column-II"),((A)[Ni(CO)_4],(p)"Octahedral paramagnetic"),((B)[Ni(CN)_4]^(-2),(q)"Square planar diamagnetic "),((C)[Ni(NH_3)_6]^(+2),(r)"Tetrahedral diamagnetic "),((D )[NiCl_4]^(-2), (s)"Tetrahedral paramagnetic"):}`

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To solve the matching question regarding the geometries and magnetic properties of the nickel complexes, we will analyze each complex in Column I and determine its corresponding match in Column II. ### Step-by-Step Solution: 1. **Complex A: [Ni(CO)₄]** - **Oxidation State**: Nickel in this complex is in the zero oxidation state (Ni^0). - **Electronic Configuration**: Ni has the configuration [Ar] 3d^8 4s^2. - **Ligand Field**: CO is a strong field ligand, which causes pairing of electrons. - **Hybridization**: The hybridization is sp³, leading to a tetrahedral geometry. - **Magnetic Behavior**: Since all electrons are paired, [Ni(CO)₄] is diamagnetic. - **Match**: A → (r) "Tetrahedral diamagnetic". 2. **Complex B: [Ni(CN)₄]²⁻** - **Oxidation State**: Nickel is in the +2 oxidation state (Ni²⁺). - **Electronic Configuration**: After losing 2 electrons, the configuration is [Ar] 3d^8. - **Ligand Field**: CN⁻ is also a strong field ligand, leading to pairing of electrons. - **Hybridization**: The hybridization is dsp², resulting in a square planar geometry. - **Magnetic Behavior**: All electrons are paired, making [Ni(CN)₄]²⁻ diamagnetic. - **Match**: B → (q) "Square planar diamagnetic". 3. **Complex C: [Ni(NH₃)₆]²⁺** - **Oxidation State**: Nickel is in the +2 oxidation state (Ni²⁺). - **Electronic Configuration**: The configuration remains [Ar] 3d^8 after losing 2 electrons. - **Ligand Field**: NH₃ is a weak field ligand, which does not cause pairing. - **Hybridization**: The hybridization is sp³d², leading to an octahedral geometry. - **Magnetic Behavior**: There are unpaired electrons, making [Ni(NH₃)₆]²⁺ paramagnetic. - **Match**: C → (p) "Octahedral paramagnetic". 4. **Complex D: [NiCl₄]²⁻** - **Oxidation State**: Nickel is in the +2 oxidation state (Ni²⁺). - **Electronic Configuration**: The configuration is [Ar] 3d^8 after losing 2 electrons. - **Ligand Field**: Cl⁻ is a weak field ligand, which does not cause pairing. - **Hybridization**: The hybridization is sp³, resulting in a tetrahedral geometry. - **Magnetic Behavior**: There are unpaired electrons, making [NiCl₄]²⁻ paramagnetic. - **Match**: D → (s) "Tetrahedral paramagnetic". ### Final Matches: - A → (r) "Tetrahedral diamagnetic" - B → (q) "Square planar diamagnetic" - C → (p) "Octahedral paramagnetic" - D → (s) "Tetrahedral paramagnetic"

To solve the matching question regarding the geometries and magnetic properties of the nickel complexes, we will analyze each complex in Column I and determine its corresponding match in Column II. ### Step-by-Step Solution: 1. **Complex A: [Ni(CO)₄]** - **Oxidation State**: Nickel in this complex is in the zero oxidation state (Ni^0). - **Electronic Configuration**: Ni has the configuration [Ar] 3d^8 4s^2. - **Ligand Field**: CO is a strong field ligand, which causes pairing of electrons. ...
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The correct order of matching of complex compound in column I with the properties in column II: {:(,"Column I",,"Column II",),((A),[Cr(NH_(3))_(6)]^(3+),(P),"Tetrahedral and paaramagnetic",),((B),[Co(CN)_(6)]^(3-),(Q),"Octahedral and diamagnetic",),((C ),[Ni(CN)_(4)]^(2-),(R ),"Octahedral and paramagnetic",),((D),[Ni(Cl)_(4)]^(2-),(S),"Square planar and diamagnetic",):}

Match the compounds listed in column I with characteristic listed in column II. {:("Column-I","Column-II"),((A)B_2H_6,(p)"Tetrahedral hybridisation"),((B)Al_2Cl_6,(q)"Trigonal planar hybridisation"),((C )BeCl_2(s),(r)"Empty orbital of central atom participate in hybridisation"),((D)(SiH_3)_3N,(s)"Two types of bonds"),(,(t)"Two type of bond angles"):}

[Cr(NH_3)_6]^(3+) is paramagnetic while [Ni(CN)_4]^(2-) is diamagnetic. Explain why?

{:("Column-I","Column-II"),((A)XeF_4,(p)sp^3d "see-saw geometry"),((B)SF_4,(q)sp^3d^2 "square planar"),((C )SF_6, (r)sp^3d^3 "distorted octahedral geometry"),((D)XeF_6,(s)sp^3d^2 "octahedral geometry"):}

Match the complexed listed column -I with type of hybridisation listed in column -II and select the correct answer using the code given below the lists : {:(,"Column"-I,,"Column"-II,),((a),[AuF_(4)]^(-),,(p)" "dsp^(2)"hybridisation",),((b),[Cu(CN)_(4)]^(3-),,(q)" "sp^(3)"hybridisation",),((c ),[Co(NH_(3))_(6)]^(3+),,(r)" "sp^(3)d^(2)"hybridisation",),((d),[Fe(H_(2)O)_(5)NO]^(2+),,(s)" "d^(2)sp^(3)"hybridisation",):}

Match the salts listed in column I with the colour of the precipitate and reagent listed in column II. {:("Column I","Column II"),((A)FeSO_4,(p)"Green precipitate with NaOH"),((B)Bi(NO_3)_3,(q)"White precipitate with" Pb(NO_3)_2),(( C)Ni(NO_3)_2,(r)"Yellow precipitate with"NH_4NO_2 and CH_3COOH "on warming"),((D)CoCl_2,(s)"Black precipitate with"H_2S),(,(t)"White precipitate with excess of water"):}

Why Ni(CO_2)_4 is tetrahedral while [Ni(CN)_4]^(2-) is square planar?

Give reason for the statement [Ni(CN)_(4)]^(2-) is diamagnetic while [NiCl_(4)]^(2-) is paramagnetic in nature .

How many of the following complexes are correctly matched with given properties ? (a) [Ni(NH_3)_6]^(2+) -Octahedral outer orbital complex and two unpaired electrons. (b) [Cr (NH_3)_6]^(3+) -Octahedral inner orbital complex and one unpaired electron. ( c) [Zn(NH_3)_6]^(2+) -Octahedral outer orbital complex and diamagnetic. (d) [Pt (NH_(3))_4]^(2+) -Square planar and diamagnetic (e) [Co (SCN)_4]^(2-) -Tetrahedral and three unpaired electrons. (f) [NiBr_2(PPh_3)_2] -Square planar and diamagnetic.

Explain the following giving reasons [NiCI_(4)]^(2-) is tetrahedral and paramagnetic whereas [Ni(CN)_(4)]^(2-) is square plannar and dimagnetic.

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