Home
Class 12
CHEMISTRY
Alkali metals oxide are obtained by comb...

Alkali metals oxide are obtained by combustion of the metals.Although Na normally gives `Na_2O_2`,it will take up further oxygen at elevated pressure and temperature to form `NaO_2`.The per and superoxides of the heavier alkalies can also be prepared by passing stoichiometric amounts of oxygen into their solution in liquid ammonia.
The different alkali metal oxides can be distinguished by reaction with water.The superoxides reacts with `CO_2` and give oxygen gas.The stability of per and superoxides is based upon that larger cation can stablise larger anion, due to larger lattice energy.
Alkali metals dissolve in liquid ammonia.Dilute solutions are dark blue in colour but as the concentration increases above 3M, the colour changes to copper bronze and the solution acquires the metallic lusture due to the formation of metal ions clusters.The solutions of alkali metals in liquid ammonia are good conductors of electricity due to the presence of ammoniated cations and ammoniated electrons.However, the conductivity decreases as the concentrations increases, since ammoniated electrons and ammoniated cation associate.
Select the correct choice for alkali metal oxides.

A

Metal oxides react with water forming only metal hydroxides

B

Metal peroxides react with hot water forming metal hydroxides and oxygen gas

C

Metal superoxides react with water forming metal hydroxides , hydrogen peroxide and `O_2` gas

D

All of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding alkali metal oxides and their reactions, we will analyze the statements provided and determine their correctness based on the information given in the paragraph. ### Step-by-Step Solution: 1. **Understanding Alkali Metal Oxides**: - Alkali metals (Group 1 metals) react with oxygen to form oxides, peroxides, and superoxides. - Sodium typically forms sodium peroxide (Na2O2) but can form sodium oxide (NaO2) under certain conditions. 2. **Reactions with Water**: - The first statement claims that metal oxides react with water to form only metal hydroxides. - This is correct as the general reaction for alkali metal oxides (MO) with water (H2O) is: \[ \text{MO} + \text{H}_2\text{O} \rightarrow 2\text{MOH} \] - Thus, the first statement is true. 3. **Reactions of Peroxides with Water**: - The second statement mentions that metal peroxides react with hot water to form metal hydroxides and oxygen gas. - The reaction for metal peroxides (M2O2) with water is: \[ \text{M}_2\text{O}_2 + 2\text{H}_2\text{O} \rightarrow 2\text{MOH} + \frac{1}{2}\text{O}_2 \] - This confirms that the second statement is also true. 4. **Reactions of Superoxides with Water**: - The third statement states that metal superoxides react with water to form metal hydroxide, hydrogen peroxide, and oxygen gas. - The reaction for metal superoxides (M2O2) with water is: \[ 2\text{MO}_2 + 2\text{H}_2\text{O} \rightarrow 2\text{MOH} + \text{H}_2\text{O}_2 + \text{O}_2 \] - This indicates that the third statement is also true. 5. **Conclusion**: - Since all three statements are correct, the answer to the question is that all of these statements regarding alkali metal oxides are true. ### Final Answer: All of the statements regarding alkali metal oxides are correct. ---

To solve the question regarding alkali metal oxides and their reactions, we will analyze the statements provided and determine their correctness based on the information given in the paragraph. ### Step-by-Step Solution: 1. **Understanding Alkali Metal Oxides**: - Alkali metals (Group 1 metals) react with oxygen to form oxides, peroxides, and superoxides. - Sodium typically forms sodium peroxide (Na2O2) but can form sodium oxide (NaO2) under certain conditions. ...
Promotional Banner

Topper's Solved these Questions

  • QUALITATIVE ANALYSIS PART 1

    RESONANCE ENGLISH|Exercise A.L.P|39 Videos
  • SOLID STATE

    RESONANCE ENGLISH|Exercise PHYSICAL CHEMITRY (SOLID STATE)|45 Videos

Similar Questions

Explore conceptually related problems

Alkali metals oxide are obtained by combustion of the metals.Although Na normally gives Na_2O_2 ,it will take up further oxygen at elevated pressure and temperature to form NaO_2 .The per and superoxides of the heavier alkalies can also be prepared by passing stoichiometric amounts of oxygen into their solution in liquid ammonia. The different alkali metal oxides can be distinguished by reaction with water.The superoxides reacts with CO_2 and give oxygen gas.The stability of per and superoxides is based upon that larger cation can stablise larger anion, due to larger lattice energy. Alkali metals dissolve in liquid ammonia.Dilute solutions are dark blue in colour but as the concentration increases above 3M, the colour changes to copper bronze and the solution acquires the metallic lusture due to the formation of metal ions clusters.The solutions of alkali metals in liquid ammonia are good conductors of electricity due to the presence of ammoniated cations and ammoniated electrons.However, the conductivity decreases as the concentrations increases, since ammoniated electrons and ammoniated cation associate. On dissolving smaller (less than 3M) amount of sodium metal in liquid ammonia at low temperature , which one of the following does not occur ?

Alkali metals oxide are obtained by combustion of the metals.Although Na normally gives Na_2O_2 ,it will take up further oxygen at elevated pressure and temperature to form NaO_2 .The per and superoxides of the heavier alkalies can also be prepared by passing stoichiometric amounts of oxygen into their solution in liquid ammonia. The different alkali metal oxides can be distinguished by reaction with water.The superoxides reacts with CO_2 and give oxygen gas.The stability of per and superoxides is based upon that larger cation can stablise larger anion, due to larger lattice energy. Alkali metals dissolve in liquid ammonia.Dilute solutions are dark blue in colour but as the concentration increases above 3M, the colour changes to copper bronze and the solution acquires the metallic lusture due to the formation of metal ions clusters.The solutions of alkali metals in liquid ammonia are good conductors of electricity due to the presence of ammoniated cations and ammoniated electrons.However, the conductivity decreases as the concentrations increases, since ammoniated electrons and ammoniated cation associate. Solution of sodium metals in liquid ammonia is strongly reducing due to the presence of :

Alkali metals oxide are obtained by combustion of the metals.Although Na normally gives Na_2O_2 ,it will take up further oxygen at elevated pressure and temperature to form NaO_2 .The per and superoxides of the heavier alkalies can also be prepared by passing stoichiometric amounts of oxygen into their solution in liquid ammonia. The different alkali metal oxides can be distinguished by reaction with water.The superoxides reacts with CO_2 and give oxygen gas.The stability of per and superoxides is based upon that larger cation can stablise larger anion, due to larger lattice energy. Alkali metals dissolve in liquid ammonia.Dilute solutions are dark blue in colour but as the concentration increases above 3M, the colour changes to copper bronze and the solution acquires the metallic lusture due to the formation of metal ions clusters.The solutions of alkali metals in liquid ammonia are good conductors of electricity due to the presence of ammoniated cations and ammoniated electrons.However, the conductivity decreases as the concentrations increases, since ammoniated electrons and ammoniated cation associate. KO_2 is used in oxygen cylinders in space and submarines because it :

Which of the following statements is wrong for the solution of alkali metals in liquids ammonia

When an alkali metal dissolves in liquid ammonia the solution can acquire different colours. Explain the reasons for this type of colour change.

How alkali metal halides can be prepared?

Alkali metals can be obtained by chemical reduction of their compounds.

Take any one alkali metal and write its reaction with Water

Take any one alkali metal and write its reaction with Oxygen

Name the ions present in solution of ammonia and alkali metals.

RESONANCE ENGLISH-RANK BOOSTER-All Questions
  1. Alkali metals oxide are obtained by combustion of the metals.Although ...

    Text Solution

    |

  2. Alkali metals oxide are obtained by combustion of the metals.Although ...

    Text Solution

    |

  3. Alkali metals oxide are obtained by combustion of the metals.Although ...

    Text Solution

    |

  4. Alkali metals oxide are obtained by combustion of the metals.Although ...

    Text Solution

    |

  5. Match the order given in column (I) with the property(les) in column (...

    Text Solution

    |

  6. Match the compounds, listed in column-I with the characteristic(s) lis...

    Text Solution

    |

  7. Match the compounds listed in colomn-I with the related uses/particula...

    Text Solution

    |

  8. The density of a salt solution is 1.13gcm^(−3) and it contains 20% o...

    Text Solution

    |

  9. The density of a salt solution is 1.13gcm^(−3) and it contains 20% o...

    Text Solution

    |

  10. How many of the following metal chlorides impart characteristic colour...

    Text Solution

    |

  11. The combustion of sodium in excess air yields a higher oxide. What is ...

    Text Solution

    |

  12. Charge on cation in product formed when BeCl2 reacts with concentrated...

    Text Solution

    |

  13. Hydrogen reacts with a metal (A) to give an ionic hydride (B).The meta...

    Text Solution

    |

  14. How many of the following nitrates of metal 'M' decompose on heating s...

    Text Solution

    |

  15. The decahydrate form of sodium carbonate i.e. washing soda on starding...

    Text Solution

    |

  16. Why Nitrogen does not form NCl(5) But phosphorous form PCl(5)? ?

    Text Solution

    |

  17. Which combination is correct for K metal

    Text Solution

    |

  18. Which combination is correct

    Text Solution

    |

  19. Aqueous solution of orthoboric acid can be titrated against sodium hyd...

    Text Solution

    |

  20. Select the correct statement about elements of group 15^(th)

    Text Solution

    |