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B^(3+) cannot exist in aqueous solution ...

`B^(3+)` cannot exist in aqueous solution because of its :

A

Strong reducing ability

B

Strong oxidizing ability

C

Small size and large charge

D

Large size and small charge

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The correct Answer is:
To determine why \( B^{3+} \) cannot exist in aqueous solution, we will analyze the properties of boron and its ionization. ### Step-by-Step Solution: 1. **Understanding the Ion**: - Boron (B) can lose three electrons to form the \( B^{3+} \) ion. This ion has a +3 oxidation state. 2. **Size of the Ion**: - Boron is a small atom. When it loses three electrons, the resulting \( B^{3+} \) ion is also very small in size. 3. **Charge Density**: - Charge density is defined as the charge of the ion divided by its radius. For \( B^{3+} \), the charge is +3, and due to its small size, the radius is also small. - Therefore, the charge density of \( B^{3+} \) is very high. 4. **Implications of High Charge Density**: - A high charge density leads to strong interactions with water molecules. Instead of remaining as a free ion in solution, \( B^{3+} \) tends to attract water molecules strongly. 5. **Hydrolysis**: - Due to the strong interaction with water, \( B^{3+} \) undergoes hydrolysis. This means it reacts with water to form other species rather than existing as \( B^{3+} \) in solution. - For example, \( BCl_3 \) can react with water to form boric acid (\( H_3BO_3 \)) and hydrochloric acid (\( HCl \)). 6. **Conclusion**: - The combination of the small size of the \( B^{3+} \) ion and its high charge density leads to its inability to exist as a free ion in aqueous solution. Instead, it hydrolyzes and forms covalent compounds. ### Final Answer: \( B^{3+} \) cannot exist in aqueous solution due to its small size and high charge density, which leads to hydrolysis and the formation of covalent compounds. ---

To determine why \( B^{3+} \) cannot exist in aqueous solution, we will analyze the properties of boron and its ionization. ### Step-by-Step Solution: 1. **Understanding the Ion**: - Boron (B) can lose three electrons to form the \( B^{3+} \) ion. This ion has a +3 oxidation state. 2. **Size of the Ion**: ...
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