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Which of the following option is correct...

Which of the following option is correctly matched ?

A

`S_3O_9` , contains no S-S linkage

B

`S_2O_6^(2-)` , contains -O-O-linkage

C

`(HPO_3)_3`, contains P-P linkage

D

`S_2O_8^(2-)` , contains S-S linkage

Text Solution

AI Generated Solution

The correct Answer is:
To determine which of the given options is correctly matched, we will analyze each compound and its corresponding structure to identify any specific linkages mentioned in the options. ### Step-by-Step Solution: 1. **Analyze S3O9**: - **Chemical Name**: Sulfur trioxide trimer. - **Structure**: The structure consists of three sulfur atoms and nine oxygen atoms. The linkages present are S-O-S, indicating that there are no S-S linkages. - **Conclusion**: The statement that S3O9 contains no S-S linkage is **correct**. 2. **Analyze S2O6^2-**: - **Chemical Name**: Dithionate. - **Structure**: The structure contains two sulfur atoms and six oxygen atoms. The linkages present are S-O, but there are no O-O linkages. - **Conclusion**: The statement that S2O6^2- contains O-O linkage is **incorrect**. 3. **Analyze HPO3 (thrice)**: - **Chemical Name**: Cyclotrimetaphosphoric acid. - **Structure**: The structure consists of phosphorus and oxygen atoms with P-O-P linkages. There are no P-P linkages present. - **Conclusion**: The statement that HPO3 contains P-P linkage is **incorrect**. 4. **Analyze S2O8^2-**: - **Chemical Name**: Peroxydisulphate or persulphate ion. - **Structure**: The structure has two sulfur atoms and eight oxygen atoms. The linkages present are S-O, and there are no S-S linkages. - **Conclusion**: The statement that S2O8^2- contains S-S linkage is **incorrect**. ### Final Conclusion: The only correct match is for **S3O9**, which contains no S-S linkage.

To determine which of the given options is correctly matched, we will analyze each compound and its corresponding structure to identify any specific linkages mentioned in the options. ### Step-by-Step Solution: 1. **Analyze S3O9**: - **Chemical Name**: Sulfur trioxide trimer. - **Structure**: The structure consists of three sulfur atoms and nine oxygen atoms. The linkages present are S-O-S, indicating that there are no S-S linkages. - **Conclusion**: The statement that S3O9 contains no S-S linkage is **correct**. ...
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