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Among the following, the species that is...

Among the following, the species that is both paramagnetic and coloured is :

A

`[MnO_4]^(2-)`

B

`[TiCl_6]^(2-)`

C

`[VO_4]^(3-)`

D

`CrO_2Cl_2`

Text Solution

Verified by Experts

The correct Answer is:
A

`[MnO_4]^(2-)` , Mn is in +6 oxidation state. Electronic configuration is `[Ar]^18 3d^1 4s^0`.As it contains one unpaired electron it is paramagnetic and green coloured because of d-d transition in visible region.
`[TiCl_6]^(2-), [VO_4]^(3-) and CrO_2Cl_2` are diamagnetic because all electrons are paired
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