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Which of the following statements is/are...

Which of the following statements is/are incorrect ?

A

In thiourea test for nitrite , a green coloured solution is obtained

B

It is not necessary to carry out the chromyl chloride test in a dry test tube

C

In `PbNO_3` , the brown ring test can be performed with its water extract

D

Suspension of `CdCO_3` gives black precipitate with sodium sulphide solution

Text Solution

AI Generated Solution

The correct Answer is:
To determine which statements are incorrect, we will analyze each statement one by one based on the information provided in the video transcript. ### Step-by-Step Solution: 1. **Statement Analysis:** - **Statement 1:** "In thiourea test for nitrite, a green colored solution is obtained." - This statement is **incorrect**. The thiourea test for nitrite actually produces a **deep red coloration** due to the formation of Fe(SCN)₃ (iron(III) thiocyanate). 2. **Statement 2:** "It is not necessary to carry out the chromyl chloride test in a dry test tube." - This statement is **incorrect**. The chromyl chloride test must be performed in a **dry test tube** because if moisture is present, chromyl chloride (CrO₂Cl₂) reacts with water to form H₂CrO₄ and HCl, which would interfere with the test. 3. **Statement 3:** "In Pb(NO₃)₂, the brown ring test can be performed with its water extract." - This statement is **incorrect**. The brown ring test cannot be performed with lead nitrate's water extract because the reaction produces PbSO₄, which is a white precipitate, thus the brown ring will not be visible. 4. **Statement 4:** "Suspension of CdCO₃ gives black precipitate with sodium sulfide solution." - This statement is **incorrect**. When CdCO₃ is treated with sodium sulfide, it produces a **yellow precipitate** of cadmium sulfide (CdS), not a black precipitate. ### Conclusion: All the statements provided in the question are incorrect. Therefore, the answer is that options A, B, C, and D are all incorrect.

To determine which statements are incorrect, we will analyze each statement one by one based on the information provided in the video transcript. ### Step-by-Step Solution: 1. **Statement Analysis:** - **Statement 1:** "In thiourea test for nitrite, a green colored solution is obtained." - This statement is **incorrect**. The thiourea test for nitrite actually produces a **deep red coloration** due to the formation of Fe(SCN)₃ (iron(III) thiocyanate). ...
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