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How many of the following pairs of ions ...

How many of the following pairs of ions can be separated by `H_2S` in dilute HCl ?
`Bi^(3+) and Sn^(4+),Al^(3+) and Hg^(2+),Cd^(2+) and Zn^(2+),Fe^(3+) and Cu^(2+), As^(3+) and Sb^(3+)`

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To determine how many pairs of ions can be separated by `H2S` in dilute `HCl`, we need to analyze the solubility of the sulfides formed from each pair of ions. The key is to identify which ions precipitate as sulfides when `H2S` is added to a solution containing them. ### Step-by-Step Solution: 1. **Identify the pairs of ions:** - Pair 1: `Bi^(3+)` and `Sn^(4+)` - Pair 2: `Al^(3+)` and `Hg^(2+)` - Pair 3: `Cd^(2+)` and `Zn^(2+)` - Pair 4: `Fe^(3+)` and `Cu^(2+)` - Pair 5: `As^(3+)` and `Sb^(3+)` 2. **Analyze each pair for precipitation with `H2S`:** - **Pair 1: `Bi^(3+)` and `Sn^(4+)`** - Both ions do not form precipitates with `H2S` in dilute `HCl`. Thus, they cannot be separated. - **Pair 2: `Al^(3+)` and `Hg^(2+)`** - `Hg^(2+)` forms a black precipitate of `HgS` when `H2S` is added, while `Al^(3+)` remains in solution. Thus, they can be separated. - **Pair 3: `Cd^(2+)` and `Zn^(2+)`** - `Cd^(2+)` forms a yellow precipitate of `CdS`, while `Zn^(2+)` remains in solution. Thus, they can be separated. - **Pair 4: `Fe^(3+)` and `Cu^(2+)`** - `Fe^(3+)` forms a black precipitate of `FeS`, while `Cu^(2+)` remains in solution. Thus, they can be separated. - **Pair 5: `As^(3+)` and `Sb^(3+)`** - Both `As^(3+)` and `Sb^(3+)` can form precipitates with `H2S`. Therefore, they cannot be separated. 3. **Count the separable pairs:** - From the analysis, we found that pairs 2, 3, and 4 can be separated by `H2S`. Therefore, there are **3 pairs** that can be separated. ### Final Answer: **3 pairs of ions can be separated by `H2S` in dilute `HCl`.**

To determine how many pairs of ions can be separated by `H2S` in dilute `HCl`, we need to analyze the solubility of the sulfides formed from each pair of ions. The key is to identify which ions precipitate as sulfides when `H2S` is added to a solution containing them. ### Step-by-Step Solution: 1. **Identify the pairs of ions:** - Pair 1: `Bi^(3+)` and `Sn^(4+)` - Pair 2: `Al^(3+)` and `Hg^(2+)` - Pair 3: `Cd^(2+)` and `Zn^(2+)` ...
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