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Amines are derivatives of ammonia and ar...

Amines are derivatives of ammonia and are classified as `1^@, 2^@ , and 3^@` Primary and secondary (but not teritary amines) form intermolecular hydrogen bonds and thus they boil at higher temperature than expected.Like ammonia, all amines are basic, although they differ in their basic nature.As amines are considered as derivatives of ammonia, quatemary ammonium salts are considered as derivatives of ammonium salts.Only the quatemary ammonium salts can show optical activity.
Methylethylpropyl amine is optically inactive because

A

It is not tetrahedral

B

Its molecules are superimposable on their mirror image

C

The enantiomers are rapidly interconverted into each other

D

the nitrogen is `sp^2` hybridized

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The correct Answer is:
To determine why methyl ethyl propyl amine is optically inactive, we can follow these steps: ### Step 1: Identify the Structure of Methyl Ethyl Propyl Amine Methyl ethyl propyl amine is a tertiary amine with the following structure: - It has three alkyl groups attached to the nitrogen atom: a methyl group (CH3), an ethyl group (C2H5), and a propyl group (C3H7). ### Step 2: Understand Chirality For a molecule to be optically active, it must have a chiral center, which is typically a carbon atom bonded to four different substituents. In the case of amines, the nitrogen atom can also be a chiral center if it is bonded to three different groups. ### Step 3: Analyze the Nitrogen Atom In methyl ethyl propyl amine, the nitrogen atom is bonded to three different alkyl groups. However, the presence of these groups does not guarantee optical activity. ### Step 4: Consider Nitrogen Inversion Tertiary amines like methyl ethyl propyl amine undergo a phenomenon known as "nitrogen inversion." This means that the nitrogen can rapidly interconvert between different spatial arrangements of the attached groups. ### Step 5: Conclusion on Optical Activity Due to nitrogen inversion, the molecule does not exist as a stable chiral form. Instead, it exists as a racemic mixture, where the enantiomers interconvert rapidly, making it optically inactive. ### Final Answer Methyl ethyl propyl amine is optically inactive because it undergoes rapid nitrogen inversion, preventing it from existing as a stable chiral compound. ---

To determine why methyl ethyl propyl amine is optically inactive, we can follow these steps: ### Step 1: Identify the Structure of Methyl Ethyl Propyl Amine Methyl ethyl propyl amine is a tertiary amine with the following structure: - It has three alkyl groups attached to the nitrogen atom: a methyl group (CH3), an ethyl group (C2H5), and a propyl group (C3H7). ### Step 2: Understand Chirality For a molecule to be optically active, it must have a chiral center, which is typically a carbon atom bonded to four different substituents. In the case of amines, the nitrogen atom can also be a chiral center if it is bonded to three different groups. ...
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Amines are derivatives of ammonia and are classified as 1^@, 2^@ , and 3^@ Primary and secondary (but not teritary amines) form intermolecular hydrogen bonds and thus they boil at higher temperature than expected.Like ammonia, all amines are basic, although they differ in their basic nature.As amines are considered as derivatives of ammonia, quatemary ammonium salts are considered as derivatives of ammonium salts.Only the quatemary ammonium salts can show optical activity. Which of the following statement is correct ?

Amines are derivatives of ammonia and are classified as 1^(@), 2^(@) , and 3^(@) , Primary and secondary (but not teritiary amines) form intermolecular hydrogen bonds and thus they boil at highter temperatures than expected. Like ammonia, all amines are basic, although they differ in their basic nature. As amines are considered as derivatives of ammonia, quaternary ammonium salts are considered as derivatives of ammonium salts. Only the quaternary ammonium salts can shown optical activity. When nitrogen is bounded to three different groups

Primary, secondary and tertiary amines may be separated by using

Primary and secondary amines can be distinguished by

Primary and secondary amines are distinguished by:

Primary and secondary amines are distinguished by :

Category of compounds which liberate ammonia from ammonium salts :

Primary, secondary and tertiary amines cannot be distinguished by the action of

Amines are basic in character because they have

Primary and secondary amines react with acid chloride or acid anhydride to form

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