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PhOHunderset(Me2SO4)overset( 2 mol NaOH...

`PhOHunderset(Me_2SO_4)overset( 2 mol NaOH ) to P ` In given reaction product P is :

A

`Ph-O-SO_2OMe`

B

`PhOMe`

C

`PhOSO_2OPh`

D

`PhMe`

Text Solution

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The correct Answer is:
To solve the question regarding the reaction of phenol (PhOH) with dimethyl sulfate (Me2SO4) in the presence of sodium hydroxide (NaOH), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are phenol (C6H5OH) and dimethyl sulfate (Me2SO4). - Sodium hydroxide (NaOH) is used as a base in this reaction. 2. **Understand the Reaction Type**: - This reaction is an example of the Williamson ether synthesis, which involves the formation of ethers from alcohols and alkyl halides or alkyl sulfates in the presence of a base. 3. **Formation of Phenoxide Ion**: - When phenol reacts with NaOH, it gets deprotonated to form the phenoxide ion (C6H5O⁻), which is a strong nucleophile. 4. **Nucleophilic Attack**: - The phenoxide ion will attack the electrophilic carbon in dimethyl sulfate. This results in the substitution of one of the methyl groups in dimethyl sulfate with the phenoxide ion. 5. **Formation of Product**: - The reaction leads to the formation of anisole (C6H5OCH3) and the by-products of the reaction, which include sodium sulfate (Na2SO4) and water (H2O). - The balanced reaction can be written as: \[ 2 \text{C}_6\text{H}_5\text{OH} + \text{Me}_2\text{SO}_4 \xrightarrow{2 \text{NaOH}} 2 \text{C}_6\text{H}_5\text{OCH}_3 + \text{Na}_2\text{SO}_4 + 2 \text{H}_2\text{O} \] 6. **Identify Product P**: - The product P formed in this reaction is anisole, which can also be represented as phenyl methyl ether (C6H5OCH3). ### Final Answer: The product P is **anisole (C6H5OCH3)**.

To solve the question regarding the reaction of phenol (PhOH) with dimethyl sulfate (Me2SO4) in the presence of sodium hydroxide (NaOH), we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - The reactants are phenol (C6H5OH) and dimethyl sulfate (Me2SO4). - Sodium hydroxide (NaOH) is used as a base in this reaction. ...
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Knowledge Check

  • Ph-C-=C-CH_(3)underset(HgSO_(4))overset(H_(2)O,H_(2)SO_(4))(to)P Major product P will be

    A
    `Ph-CH_(2)-overset(O)overset(||)(C)-CH_(3)`
    B
    `Ph-overset(O)overset(||)(C)-CH_(2)-CH_(3)`
    C
    `Ph-CH=overset(OH)overset(|)(C)-CH_(3)`
    D
    `Ph-overset(OH)overset(|)(C)=CH-CH_(3)`
  • H - C = C- H underset(H_2SO_4) overset(HgSO_4)to (A) underset((2) H_3O^(o+)) overset((1) NH_3 + HCN)to(B) , Product (B) of given reaction is :

    A
    Glycine
    B
    Alanine
    C
    valine
    D
    Leucine
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