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The correct order of SN 2//E2 ratio for ...

The correct order of `S_N 2//E2` ratio for the % yield of product of the following halide is-
(P)`CH_3-CH-undersetunderset(I)(|)oversetoverset(Ph)(|)C-CH_3` , (Q)`CH_3-undersetunderset(Ph)(|)CH-undersetunderset(I)(|)CH-CH_3`
(R)`CH_3-CH_2-I` , (S)`CH_3-CH-undersetundersetI|CH-CH_3`

A

RgtSgtQgtP

B

RgtQgtSgtP

C

PgtRgtSgtQ

D

QgtPgtRgtS

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The correct Answer is:
To determine the correct order of the `S_N2/E2` ratio for the percentage yield of products from the given halides (P, Q, R, and S), we need to analyze each compound based on the factors that influence the `S_N2` and `E2` mechanisms. ### Step-by-Step Solution: 1. **Identify the Structure of Each Halide:** - **P:** `CH3-CH(I)(Ph)-C-CH3` (Tertiary halide) - **Q:** `CH3-(Ph)(I)-CH-CH3` (Secondary halide with a phenyl group) - **R:** `CH3-CH2-I` (Primary halide) - **S:** `CH3-CH(I)-CH-CH3` (Secondary halide) 2. **Determine the Degree of Each Halide:** - **R** is a primary halide, which is most favorable for the `S_N2` mechanism. - **S** is a secondary halide, which can undergo both `S_N2` and `E2`, but is more favorable for `E2` due to branching. - **Q** is a secondary halide but has a phenyl group, which decreases the `S_N2` reactivity. - **P** is a tertiary halide, which is least favorable for `S_N2` and more favorable for `E2`. 3. **Analyze the Factors Affecting `S_N2` and `E2`:** - **For `S_N2`:** The reaction is favored in primary halides and decreases in secondary and tertiary halides. - **For `E2`:** The reaction is favored in more substituted (branched) alkyl halides. 4. **Rank the Halides Based on `S_N2/E2` Ratio:** - **R** (Primary halide) will have the highest `S_N2/E2` ratio. - **S** (Secondary halide) will have the next highest ratio, but still significant `E2` reactivity. - **Q** (Secondary halide with phenyl) will have a lower `S_N2` ratio due to steric hindrance. - **P** (Tertiary halide) will have the lowest `S_N2/E2` ratio as it favors `E2`. 5. **Final Order:** The correct order of `S_N2/E2` ratio from highest to lowest is: - R > S > Q > P ### Conclusion: The order of `S_N2/E2` ratio for the percentage yield of products from the halides is: **R > S > Q > P**

To determine the correct order of the `S_N2/E2` ratio for the percentage yield of products from the given halides (P, Q, R, and S), we need to analyze each compound based on the factors that influence the `S_N2` and `E2` mechanisms. ### Step-by-Step Solution: 1. **Identify the Structure of Each Halide:** - **P:** `CH3-CH(I)(Ph)-C-CH3` (Tertiary halide) - **Q:** `CH3-(Ph)(I)-CH-CH3` (Secondary halide with a phenyl group) - **R:** `CH3-CH2-I` (Primary halide) ...
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