Home
Class 12
CHEMISTRY
Statement-1:When 3-Chlorobut-1-ene react...

Statement-1:When 3-Chlorobut-1-ene react `H_2O` then give four products.
Statement-2:Intermediate is carbocation and it show resonance and recemisation.

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1

C

Statement-1 is True, Statement-2 is False.

D

Statement-1 is False, Statement-2 is True.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of 3-Chlorobut-1-ene with water and the resulting products, we can break down the problem step by step. ### Step-by-Step Solution: 1. **Identify the Structure of 3-Chlorobut-1-ene:** - The structure of 3-Chlorobut-1-ene can be drawn as follows: ``` CH2=CH-CH(Cl)-CH3 ``` - Here, the double bond is between the first and second carbon atoms, and the chlorine atom is attached to the third carbon. 2. **Reaction with Water:** - When 3-Chlorobut-1-ene reacts with water (in the presence of an acid, H⁺), a nucleophilic substitution reaction occurs. - The chlorine atom (Cl) is a good leaving group and will leave, forming a carbocation intermediate. 3. **Formation of Carbocation:** - The carbocation formed after the departure of Cl is: ``` CH2=CH-CH⁺-CH3 ``` - This carbocation is a secondary carbocation and is stabilized by resonance with the double bond. 4. **Resonance Stabilization:** - The carbocation can undergo resonance, which allows for the delocalization of the positive charge: ``` CH2=CH-CH⁺-CH3 ↔ CH3-CH⁺-CH=CH2 ``` - This resonance leads to different structural forms of the carbocation. 5. **Nucleophilic Attack:** - The water molecule (acting as a nucleophile) can attack the carbocation, leading to the formation of alcohols. - Depending on the site of attack, different products can be formed. 6. **Chiral Center Formation:** - The product formed from the nucleophilic attack will have a chiral center: ``` CH3-CH(OH)-CH2-CH3 ``` - This chiral center can exist in two enantiomeric forms (R and S configurations). 7. **Geometric Isomerism:** - The presence of the double bond in the product allows for geometric isomerism (cis and trans forms). - Thus, we can have two geometric isomers from the product. 8. **Total Products:** - From the chiral center, we get 2 enantiomers. - From the geometric isomerism, we also get 2 isomers. - Therefore, the total number of products = 2 (from chiral center) + 2 (from geometric isomerism) = 4 products. ### Conclusion: - **Statement 1** is true: 3-Chlorobut-1-ene reacts with water to give four products. - **Statement 2** is also true: The intermediate is a carbocation that shows resonance and racemization. ### Final Answer: Both statements are true, and Statement 2 is the correct explanation for Statement 1. ---

To solve the question regarding the reaction of 3-Chlorobut-1-ene with water and the resulting products, we can break down the problem step by step. ### Step-by-Step Solution: 1. **Identify the Structure of 3-Chlorobut-1-ene:** - The structure of 3-Chlorobut-1-ene can be drawn as follows: ``` CH2=CH-CH(Cl)-CH3 ...
Promotional Banner

Topper's Solved these Questions

  • QUALITATIVE ANALYSIS PART 1

    RESONANCE ENGLISH|Exercise A.L.P|39 Videos
  • SOLID STATE

    RESONANCE ENGLISH|Exercise PHYSICAL CHEMITRY (SOLID STATE)|45 Videos

Similar Questions

Explore conceptually related problems

Ethylene and H_2O_2 react to give

Statement-1:Reduction of But-2-yne of Na/liq. NH_3 gives trans-But-2-ene. Statement-2: It is an example of 'anti' addition.

Statement-1: and Statement-2: Conjugate base of phenol is resonance stabilized

When but -3-en-2-ol reacts with aq HBr , we get

Statement-1 Hydration of alkenes may give more than one type of alcohol Statement -2 Carbocation intermediate may show rearrangement

A : When 3,3-dimethyl butan - 2 - ol is heated in presence of concentrated H_(2)SO_(4) then 2, 3-dimethyl but -2-ene is formed as major product . R : In this reaction , carbocation is formed as an intermediate

Statement-1: When PhCHO is made to react in D_(2)O , deuterium in incorporated in product in Cannizzaro reaction. and Statement-2: In cannizzaro reaction transfer of hydride takes place from one molecule to other.

Statement-1: Valence factor of H_(2)O_(2) is always 2. Statement-2: In redox reaction change of oxidation state per molecule is 2.

Statement-1: Bridge head carbocation is less stable than Bridge head carbanion. and Statement-2: C atom in carbocation is sp^(2) generally hybridized.

Statement -1 : When phenol is treated with PBr_(3) is gives bromobenzene. Statement -2 It is an example of nucleophilic substitution

RESONANCE ENGLISH-RANK BOOSTER-All Questions
  1. Which of the following can't be prepared by the typical Williamson rea...

    Text Solution

    |

  2. Here P is/are :

    Text Solution

    |

  3. Statement-1:When 3-Chlorobut-1-ene react H2O then give four products. ...

    Text Solution

    |

  4. 100g of salt is present in 500g of solution. Calculate the mass percen...

    Text Solution

    |

  5. Read the following reaction Compound 'T' is

    Text Solution

    |

  6. What is the mole fraction of glucose in 30% w/W glucose solution ?

    Text Solution

    |

  7. What is the mole fraction of glucose in 35% w/W glucose solution ?

    Text Solution

    |

  8. A hydrocarbon (X) of the formula C6H12 does not react with bromine wa...

    Text Solution

    |

  9. A hydrocarbon (X) of the formula C6H12 does not react with bromine wa...

    Text Solution

    |

  10. A hydrocarbon (X) of the formula C6H12 does not react with bromine wa...

    Text Solution

    |

  11. A partially racemised (+2) 2-Bromooctane on reaction with aq. NaOH in ...

    Text Solution

    |

  12. A partially racemised (+) - 2-bromo-octane (2^@ RX) on reaction with a...

    Text Solution

    |

  13. Find the mole fraction of solute in its 7 molal aqueous solution.

    Text Solution

    |

  14. Find the mole fraction of solute in its 8 molal aqueous solution.

    Text Solution

    |

  15. Find the mole fraction of solute in its 9 molal aqueous solution.

    Text Solution

    |

  16. Calculate the weight of lime (CaO) obtained by heating 240kg of 95% pu...

    Text Solution

    |

  17. Ether and alcohol are isomers.

    Text Solution

    |

  18. In the given reaction how many products are expected.

    Text Solution

    |

  19. What is the mole fraction of glucose in 50% w/W glucose solution ?

    Text Solution

    |

  20. Find the mole fraction of solute in its 10 molal aqueous solution.

    Text Solution

    |