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Statement-1:Reduction of But-2-yne of Na...

Statement-1:Reduction of But-2-yne of Na/liq. `NH_3` gives
trans-But-2-ene.
Statement-2: It is an example of 'anti' addition.

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT
a correct explanation for Statement-1

C

Statement-1 is True, Statement-2 is False.

D

Statement-1 is False, Statement-2 is True.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both statements regarding the reduction of But-2-yne using sodium (Na) in liquid ammonia (NH₃) and determine their validity. ### Step-by-Step Solution: 1. **Identify the Compound**: - But-2-yne is represented as CH₃C≡CCH₃. It is an alkyne with a triple bond between the second and third carbon atoms. 2. **Understand the Reaction Conditions**: - The reaction involves sodium metal in liquid ammonia, which is known to facilitate the Birch reduction. This process is used to reduce alkynes to alkenes. 3. **Reaction Mechanism**: - In the Birch reduction, the triple bond of the alkyne undergoes reduction. The sodium donates electrons, and in the presence of liquid ammonia, protons (H⁺) are added to the alkene formed. 4. **Formation of Product**: - The reduction of But-2-yne leads to the formation of trans-But-2-ene (CH₃CH=CHCH₃). The structure of trans-But-2-ene has the two methyl (CH₃) groups on opposite sides of the double bond. 5. **Determine Stereochemistry**: - The formation of trans-But-2-ene indicates that the reaction proceeds via an anti-addition mechanism. This means that the addition of hydrogen atoms occurs on opposite sides of the double bond, resulting in the trans configuration. 6. **Evaluate the Statements**: - **Statement 1**: "Reduction of But-2-yne by Na/liquid NH₃ gives trans-But-2-ene." - This statement is **True**. - **Statement 2**: "It is an example of 'anti' addition." - This statement is also **True** as the formation of trans-But-2-ene is a result of anti-addition. 7. **Conclusion**: - Both statements are true, and Statement 2 correctly explains Statement 1. Therefore, the answer is that both statements are true, and Statement 2 is the correct explanation for Statement 1. ### Final Answer: - Statement 1 is true. Statement 2 is true and is a correct explanation for Statement 1.
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