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Statement-1:Polyacylation in benzene doe...

Statement-1:Polyacylation in benzene does not occur during Friedal Craft's acylation.
Statement-2:As the product ketone is much more reactive than starting material.

A

Statement-1 is True, Statement-2 is True, Statement-2 is a correct explanation for Statement-1

B

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1

C

Statement-1 is True, Statement-2 is False.

D

Statement-1 is False, Statement-2 is True.

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze both statements regarding Friedel-Crafts acylation and determine their validity. ### Step-by-Step Solution: 1. **Understanding Friedel-Crafts Acylation**: - Friedel-Crafts acylation is a reaction where an acyl group (RCO-) is introduced into an aromatic ring (like benzene) using an acyl chloride and a Lewis acid catalyst (like AlCl3). - The general reaction can be represented as: \[ \text{Benzene} + \text{RCOCl} \xrightarrow{\text{AlCl}_3} \text{Acylated Benzene} \] 2. **Analyzing Statement 1**: - **Statement 1**: "Polyacylation in benzene does not occur during Friedel-Crafts acylation." - Polyacylation refers to the introduction of more than one acyl group onto the benzene ring. - In Friedel-Crafts acylation, the acyl group is an electron-withdrawing group due to the carbonyl (C=O) bond. This reduces the electron density on the aromatic ring, making it less reactive towards further electrophilic substitution. - Therefore, polyacylation does not occur because the first acylation deactivates the ring for further substitutions. - **Conclusion**: Statement 1 is **True**. 3. **Analyzing Statement 2**: - **Statement 2**: "As the product ketone is much more reactive than the starting material." - The product of Friedel-Crafts acylation is a ketone, which is indeed less reactive than benzene due to the presence of the electron-withdrawing carbonyl group. - The ketone decreases the electron density on the aromatic ring, making it less reactive towards further electrophilic attack. - **Conclusion**: Statement 2 is **False**. 4. **Final Evaluation**: - Based on the analysis: - Statement 1 is **True**. - Statement 2 is **False**. - The correct answer is **Option C**: Statement 1 is true and Statement 2 is false.

To solve the question, we need to analyze both statements regarding Friedel-Crafts acylation and determine their validity. ### Step-by-Step Solution: 1. **Understanding Friedel-Crafts Acylation**: - Friedel-Crafts acylation is a reaction where an acyl group (RCO-) is introduced into an aromatic ring (like benzene) using an acyl chloride and a Lewis acid catalyst (like AlCl3). - The general reaction can be represented as: \[ ...
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