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The compound C8H9Cl(A) on treatments wit...

The compound `C_8H_9Cl(A)` on treatments with KCN followed by hydrolysis gives `C_9H_10O_2(B)`.Ammonium salt of B on dry distillation yields C.Which reacts with alkaline solution of bromine to gives `C_8H_11N`.(D),Another compound E `(C_6H_10O)` is obtained by the action of nitrous acid on D. or by the action of aquouspotash on A,E on oxidation gives `F(C_8H_10O)` Which gives the inner anhydride G on heating. The compound D is reaction with `CHCl_3+NaOH` gives a compound H.
The compound A on reaction with AgCN gives :

A

Compound H

B

Compound B

C

Compound G

D

Compound D

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To solve the problem step-by-step, we will analyze the reactions and compounds mentioned in the question systematically. ### Step 1: Identify Compound A The compound `C8H9Cl (A)` reacts with `KCN` followed by hydrolysis to yield `C9H10O2 (B)`. - The presence of chlorine suggests that `A` could be a benzyl chloride derivative. A plausible structure for `A` could be `C6H5CH2Cl` (benzyl chloride) or a similar compound. ### Step 2: Reaction of A with KCN and Hydrolysis When `A` reacts with `KCN`, the chlorine is replaced by a cyano group, forming an intermediate which upon hydrolysis gives `B (C9H10O2)`. - The hydrolysis of the cyano group leads to the formation of a carboxylic acid. Thus, `B` could be `C6H5CH2COOH` (benzoic acid derivative). ### Step 3: Formation of Compound C The ammonium salt of `B` undergoes dry distillation to yield `C`. - The dry distillation of an ammonium salt of a carboxylic acid typically yields an amine. Thus, `C` could be `C6H5CH2NH2` (benzylamine). ### Step 4: Reaction of C with Alkaline Bromine `C` reacts with an alkaline solution of bromine to give `C8H11N (D)`. - This reaction is likely a bromination of the amine, resulting in a secondary amine. Thus, `D` could be `C6H5CH(CH3)NH2` (a substituted amine). ### Step 5: Formation of Compound E Compound `E (C6H10O)` is obtained by the action of nitrous acid on `D` or by the action of aqueous potash on `A`. - The reaction of a primary amine with nitrous acid typically yields an alcohol. Thus, `E` could be `C6H5C(OH)(CH3)`. ### Step 6: Oxidation of E to Form F `E` on oxidation gives `F (C8H10O)`. - The oxidation of an alcohol typically results in a ketone or aldehyde. Thus, `F` could be `C6H5C(=O)CH3`. ### Step 7: Heating F to Form G `F` gives an inner anhydride `G` on heating. - The heating of a compound with two carboxylic acid groups or derivatives can lead to the formation of an anhydride. Thus, `G` could be an anhydride derived from `F`. ### Step 8: Reaction of D with CHCl3 + NaOH The compound `D` reacts with `CHCl3 + NaOH` to give compound `H`. - This is a classic carbylamine reaction, where an amine reacts with chloroform and a base to form isocyanides. Thus, `H` could be `C6H5C(CH3)N=C=O`. ### Step 9: Reaction of A with AgCN The compound `A` on reaction with `AgCN` gives: - The reaction of an alkyl halide with `AgCN` typically yields an isocyanide. Thus, `A` gives the same isocyanide as `H`. ### Final Summary of Compounds - **A**: C8H9Cl (Benzyl chloride) - **B**: C9H10O2 (Benzoic acid derivative) - **C**: C8H11N (Benzylamine) - **D**: C8H11N (Substituted amine) - **E**: C6H10O (Alcohol) - **F**: C8H10O (Ketone/Aldehyde) - **G**: Inner anhydride - **H**: Isocyanide

To solve the problem step-by-step, we will analyze the reactions and compounds mentioned in the question systematically. ### Step 1: Identify Compound A The compound `C8H9Cl (A)` reacts with `KCN` followed by hydrolysis to yield `C9H10O2 (B)`. - The presence of chlorine suggests that `A` could be a benzyl chloride derivative. A plausible structure for `A` could be `C6H5CH2Cl` (benzyl chloride) or a similar compound. ### Step 2: Reaction of A with KCN and Hydrolysis When `A` reacts with `KCN`, the chlorine is replaced by a cyano group, forming an intermediate which upon hydrolysis gives `B (C9H10O2)`. ...
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The compound C_8H_9Cl(A) on treatments with KCN followed by hydrolysis gives C_9H_10O_2(B) .Ammonium salt of B on dry distillation yields C.Which reacts with alkaline solution of bromine to gives C_8H_11N .(D),Another compound E (C_6H_10O) is obtained by the action of nitrous acid on D. or by the action of aquouspotash on A,E on oxidation gives F(C_8H_10O) Which gives the inner anhydride G on heating. The compound D is reaction with CHCl_3+NaOH gives a compound H.The structure of H.

The compound C_8H_9Cl(A) on treatments with KCN followed by hydrolysis gives C_9H_10O_2(B) .Ammonium salt of B on dry distillation yields C.Which reacts with alkaline solution of bromine to gives C_8H_11N .(D)Another compound E is obtained by the action of nitrous acid on D. E on oxidation gives F which gives the inner anhydride G on heating. The Compound A is :

Compound (A) C_(8)H_(9)Br . Gives a white precipitate when warmed with alcoholic AgNO_(3) . Oxidation of (A) gives an acid (B). C_(8)H_(6)O_(4) . (B) easily forms anhydride on heating. Identify the compound (A)

Compound (A) C_(8)H_(9)Br . Gives a white precipitate when warmed with alcoholic AgNO_(3) . Oxidation of (A) gives an acid (B). C_(8)H_(6)O_(4) . (B) easily forms anhydride on heating. Identify the compound (A)

A hydrocation (A) (C_(8) H_(10)) (E) is a stream volatile compound and on nitration gives two mononitro derivatives. (A) gives the following reactions. Compound (D) is:

A hydrocation (A) (C_(8) H_(10)) (E) is a stream volatile compound and on nitration gives two mononitro derivatives. (A) gives the following reactions. Compound (C) is:

A hydrocation (A) (C_(8) H_(10)) (E) is a stream volatile compound and on nitration gives two mononitro derivatives. (A) gives the following reactions. Compound (B) is:

A hydrocation (A) (C_(8) H_(10)) (E) is a stream volatile compound and on nitration gives two mononitro derivatives. (A) gives the following reactions. Compound (E) is:

A hydrocation (A) (C_(8) H_(10)) (E) is a stream volatile compound and on nitration gives two mononitro derivatives. (A) gives the following reactions. Compound (A) is:

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