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Select the correct statement about the ...

Select the correct statement about the following reaction
`CH_3-undersetunderset(CH_3)(|)CH-CH_2-CH=CH_2overset(H_2//Ni)to(Y)overset(Cl_2//hv)to`Monochloro products

A

The reactant (X) has four positional isomers ( includeing 'X' itself)

B

The hydrogenated product Y has three positional isomers

C

Four monochloro products are formed which are all positional isomers

D

Two alkyne can given Y on hydrogenation

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AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the given reaction step by step. ### Step 1: Identify the Reactant The reactant is given as: \[ \text{CH}_3-\text{C}(\text{CH}_3)-\text{CH}_2-\text{CH}=\text{CH}_2 \] This can be represented structurally as: ``` CH3 | CH3 - C - CH2 - CH = CH2 ``` This compound is a substituted alkene. ### Step 2: Hydrogenation Reaction When the reactant is treated with hydrogen (H₂) in the presence of nickel (Ni), a hydrogenation reaction occurs. This means that the double bond in the alkene will be converted into a single bond, resulting in an alkane. The product after hydrogenation (let's call it Y) will be: \[ \text{CH}_3-\text{C}(\text{CH}_3)-\text{CH}_2-\text{CH}_2-\text{CH}_3 \] This can be represented structurally as: ``` CH3 | CH3 - C - CH2 - CH2 - CH3 ``` ### Step 3: Monochlorination Reaction Next, the product Y undergoes monochlorination when treated with chlorine (Cl₂) under UV light (hv). Monochlorination means that one hydrogen atom in the alkane is replaced by a chlorine atom. To determine the possible monochlorinated products, we need to identify all the unique positions where chlorine can be substituted. ### Step 4: Identify Monochlorinated Products 1. Chlorine at the terminal CH2 group: \[ \text{CH}_3-\text{C}(\text{CH}_3)-\text{CH}_2-\text{CH}_2\text{Cl} \] 2. Chlorine at the second CH2 group: \[ \text{CH}_3-\text{C}(\text{CH}_3)-\text{CH}\text{Cl}-\text{CH}_2-\text{CH}_3 \] 3. Chlorine at the third carbon (attached to the central carbon): \[ \text{CH}_3-\text{C}(\text{CH}_3)-\text{C}\text{Cl}-\text{CH}_2-\text{CH}_3 \] 4. Chlorine at the second carbon (attached to the CH3 group): \[ \text{CH}_3-\text{C}\text{Cl}-\text{CH}_2-\text{CH}_2-\text{CH}_3 \] 5. Chlorine at the terminal CH3 group: \[ \text{CH}_3\text{Cl}-\text{C}(\text{CH}_3)-\text{CH}_2-\text{CH}_2-\text{CH}_3 \] Thus, we can conclude that there are **five unique monochlorinated products**. ### Step 5: Analyze the Statements Now, we need to analyze the statements provided in the question: 1. **Statement about positional isomers of reactant X**: The reactant has more than four positional isomers. 2. **Statement about the hydrogenated product Y**: Y has two positional isomers. 3. **Statement about monochlorinated products**: There are five monochlorinated products. 4. **Statement about alkynes forming Y**: Two alkynes can yield Y upon hydrogenation. ### Conclusion Based on our analysis: - The first statement is incorrect (it has more than four). - The second statement is incorrect (it has two, not three). - The third statement is correct (five monochlorinated products). - The fourth statement is correct (two alkynes can yield Y). Therefore, the correct answer is that the last two statements are correct.

To solve the problem, we need to analyze the given reaction step by step. ### Step 1: Identify the Reactant The reactant is given as: \[ \text{CH}_3-\text{C}(\text{CH}_3)-\text{CH}_2-\text{CH}=\text{CH}_2 \] This can be represented structurally as: ``` CH3 ...
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