Home
Class 12
CHEMISTRY
An aromatic compound T (C10H10O2) gives ...

An aromatic compound T `(C_10H_10O_2)` gives 2 moles of `CHI_2` and compound U `(C_8H_4O_4Na)` on treatment with `I_2`.and NaOH . After acidification U gives two mononitro products on nitration.
Compound U is

A

B

C

D

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the structure of compound U (C8H4O4Na) based on the information provided. Here’s a step-by-step breakdown of the solution: ### Step 1: Analyze the given information - We have an aromatic compound T with the formula C10H10O2. - Upon treatment with I2 and NaOH, compound T yields 2 moles of CHI2 and compound U (C8H4O4Na). - After acidification, compound U can undergo nitration to give two mononitro products. ### Step 2: Determine the structure of compound T - The molecular formula C10H10O2 suggests that compound T is likely a substituted aromatic compound. - The presence of 2 moles of CHI2 indicates that there are two methyl groups adjacent to a carbonyl group (as the reaction involves the formation of iodoform). ### Step 3: Identify the structure of compound U - After the reaction, compound U has the formula C8H4O4Na. This suggests that U is a sodium salt of a dicarboxylic acid. - The presence of two carboxylate groups (from the formula) indicates that U could be a derivative of phthalic acid. ### Step 4: Consider the nitration of compound U - The fact that U gives two mononitro products upon nitration suggests that U has two positions available for substitution on the aromatic ring. - This is consistent with the structure of sodium phthalate (the sodium salt of phthalic acid), which has two available positions for nitration. ### Step 5: Conclude the structure of compound U - Based on the above analysis, compound U is likely sodium phthalate (C8H4O4Na). ### Final Answer Compound U is sodium phthalate (C8H4O4Na). ---

To solve the problem, we need to determine the structure of compound U (C8H4O4Na) based on the information provided. Here’s a step-by-step breakdown of the solution: ### Step 1: Analyze the given information - We have an aromatic compound T with the formula C10H10O2. - Upon treatment with I2 and NaOH, compound T yields 2 moles of CHI2 and compound U (C8H4O4Na). - After acidification, compound U can undergo nitration to give two mononitro products. ### Step 2: Determine the structure of compound T ...
Promotional Banner

Topper's Solved these Questions

  • QUALITATIVE ANALYSIS PART 1

    RESONANCE ENGLISH|Exercise A.L.P|39 Videos
  • SOLID STATE

    RESONANCE ENGLISH|Exercise PHYSICAL CHEMITRY (SOLID STATE)|45 Videos

Similar Questions

Explore conceptually related problems

The compound which gives H_2O_2 on treatment with dilute acid is

An aromatic compound (A), C_(7),H_(6)Cl_(2) gives AgCl on boiling with alcoholic AgNO_(3) soln. And yields C_(7)H_(7)Ocl on treatment with NaOH. (A) on oxidation gives a monochlorobenzoic acid which affords only the monoderivative on nitration the compound (A) is

A hydrocation (A) (C_(8) H_(10)) (E) is a stream volatile compound and on nitration gives two mononitro derivatives. (A) gives the following reactions. Compound (C) is:

A hydrocation (A) (C_(8) H_(10)) (E) is a stream volatile compound and on nitration gives two mononitro derivatives. (A) gives the following reactions. Compound (B) is:

A hydrocation (A) (C_(8) H_(10)) (E) is a stream volatile compound and on nitration gives two mononitro derivatives. (A) gives the following reactions. Compound (D) is:

A hydrocation (A) (C_(8) H_(10)) (E) is a stream volatile compound and on nitration gives two mononitro derivatives. (A) gives the following reactions. Compound (E) is:

A hydrocation (A) (C_(8) H_(10)) (E) is a stream volatile compound and on nitration gives two mononitro derivatives. (A) gives the following reactions. Compound (A) is:

An aromatic compound 'X' (C_9H_8O_3) turns blue litmus to red.It gives yellow precipitate with I_2//NaOH and forms Y (C_8H_5O_4) . Y forms three mononitro isomeric products. Identify X.

An organic compound X (C_(4)H_(8)O_(2)) gives positive test with NaOH and Phenopthalein. Structure of X will be:

RESONANCE ENGLISH-RANK BOOSTER-All Questions
  1. How much amount of CaCO3 in gram having percentage purity 50 per cent ...

    Text Solution

    |

  2. Give a chemical test to distinguish between a ethanal and propanal ?

    Text Solution

    |

  3. An aromatic compound T (C10H10O2) gives 2 moles of CHI2 and compound U...

    Text Solution

    |

  4. Column I may match with more than one conditions of column II. {:("C...

    Text Solution

    |

  5. X(C8H14) by ozonolysis forms Y[C8H14O2].Y on reaction with NaOI follow...

    Text Solution

    |

  6. Calculate the mass of iron which will be converted into its oxide (Fe3...

    Text Solution

    |

  7. Calculate the mass of iron which will be converted into its oxide (Fe3...

    Text Solution

    |

  8. Calculate the mass of iron which will be converted into its oxide (Fe3...

    Text Solution

    |

  9. How many alkenes can be hydrogenated to give an alkane with molecular ...

    Text Solution

    |

  10. How will you prepare acetone from Acetyl chloride ?

    Text Solution

    |

  11. Which of the following set gives the product that give two monochloro ...

    Text Solution

    |

  12. Which of the following combination gives homocyclic unsaturated produc...

    Text Solution

    |

  13. Give the correct set for the product which can be obtained by the hydr...

    Text Solution

    |

  14. Calculate the mass of iron which will be converted into its oxide (Fe3...

    Text Solution

    |

  15. Which carbonyl group is protonated most readily in acidic solution, bu...

    Text Solution

    |

  16. PhCOCHBr(2)overset(OH^(-))toAoverset(OH^(-))toBoverset(H^(+))toC The...

    Text Solution

    |

  17. The product of the following reaction is

    Text Solution

    |

  18. Which step is not feasible in the following loop ?

    Text Solution

    |

  19. How will you prepare Aspirin from Salicylic Acid ? Give two uses of As...

    Text Solution

    |

  20. PhCHO+(CH3CO)2Ooverset(CH3COONa)toAoverset(HBr)toB The product B is

    Text Solution

    |