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X(C8H14) by ozonolysis forms Y[C8H14O2]....

`X(C_8H_14)` by ozonolysis forms `Y[C_8H_14O_2]`.Y on reaction with NaOI followed by acidification gives `CHI_3` and compound Z on strong heating froms W.
`{:("Column-I","Column-II"),((A)"Compound X","(p)Bayer's Test"),((B)"Compound Y",(q)NaHCO_3),(( C)"Compound Z","(r)2, 4-DNP"),((D)"Compound W","(s)Iodoform Test"),(,"(t)Na Metal"):}`

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To solve the problem, we need to identify the compounds X, Y, Z, and W based on the information given about their structures and reactions. Let's break it down step by step. ### Step 1: Identify Compound X (C8H14) - We know that compound X is an alkene with the formula C8H14. - Ozonolysis of alkenes typically breaks the double bond and adds oxygen to form carbonyl compounds. - Given that ozonolysis of X forms Y (C8H14O2), we can deduce that X is likely a cyclic alkene due to the presence of a symmetrical structure. - The structure of X can be drawn as a symmetrical cyclic alkene, such as 1,2-dimethylcyclohexene. **Hint:** Look for a symmetrical structure that fits the formula C8H14. ### Step 2: Identify Compound Y (C8H14O2) - Ozonolysis of X results in Y, which has the formula C8H14O2. - The ozonolysis reaction typically converts double bonds into carbonyl groups (C=O). - Thus, Y is likely a dicarbonyl compound formed from the cleavage of the double bond in X. **Hint:** Consider the products of ozonolysis and how they relate to the structure of X. ### Step 3: Identify Compound Z - Y reacts with NaOI followed by acidification to yield CHI3 and compound Z. - The formation of CHI3 indicates that Z must contain a methyl ketone functional group (as iodoform test is positive for methyl ketones). - Since Y has two carbonyl groups, Z is likely a carboxylic acid formed from the oxidation of Y. **Hint:** Look for a compound that can yield CHI3 upon reaction with NaOI and acidification. ### Step 4: Identify Compound W - Z, upon strong heating, forms W. - Since Z is a carboxylic acid, heating it can lead to decarboxylation or rearrangement to form a simpler compound. - W is likely a hydrocarbon or a simpler ketone. **Hint:** Consider the products of thermal decomposition of carboxylic acids. ### Step 5: Match Compounds with Tests Now we need to match the compounds with the tests provided in Column-II. - **Compound X (C8H14)**: This will give a positive result for Bayer's Test (p) because it contains a carbon-carbon double bond. - **Compound Y (C8H14O2)**: This will give a positive result for 2,4-DNP test (r) as it contains carbonyl groups. - **Compound Z**: This will give a positive result for NaHCO3 test (q) because it is a carboxylic acid. - **Compound W**: This will give a positive result for Iodoform Test (s) if it contains a methyl ketone. ### Final Answers: - **A**: Compound X → (p) Bayer's Test - **B**: Compound Y → (r) 2, 4-DNP Test - **C**: Compound Z → (q) NaHCO3 Test - **D**: Compound W → (s) Iodoform Test ### Summary of Identifications: - **X**: 1,2-dimethylcyclohexene - **Y**: Dicarbonyl compound - **Z**: Carboxylic acid - **W**: A simpler ketone or hydrocarbon

To solve the problem, we need to identify the compounds X, Y, Z, and W based on the information given about their structures and reactions. Let's break it down step by step. ### Step 1: Identify Compound X (C8H14) - We know that compound X is an alkene with the formula C8H14. - Ozonolysis of alkenes typically breaks the double bond and adds oxygen to form carbonyl compounds. - Given that ozonolysis of X forms Y (C8H14O2), we can deduce that X is likely a cyclic alkene due to the presence of a symmetrical structure. - The structure of X can be drawn as a symmetrical cyclic alkene, such as 1,2-dimethylcyclohexene. ...
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