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PhCHO+(CH3CO)2Ooverset(CH3COONa)toAovers...

`PhCHO+(CH_3CO)_2Ooverset(CH_3COONa)toAoverset(HBr)toB`
The product B is

A

`PhCH=CHCH_2Br`

B

`Phundersetunderset(Br)(|)CH-CH_2-COOH`

C

`PhCH_2CH(Br)COOH`

D

PhCH=CH-COBr

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will follow the steps of the reaction sequence provided in the question. ### Step 1: Reaction of Benzaldehyde with Acetic Anhydride - **Reactants**: Benzaldehyde (PhCHO) and Acetic Anhydride ((CH₃CO)₂O) in the presence of Sodium Acetate (CH₃COONa). - **Mechanism**: The sodium acetate acts as a catalyst for the reaction, facilitating the formation of an intermediate product through a condensation reaction. This leads to the formation of an enol acetate. The reaction can be represented as: \[ \text{PhCHO} + \text{(CH}_3\text{CO)}_2\text{O} \xrightarrow{\text{CH}_3\text{COONa}} \text{A} \] The product A is likely to be Cinnamic Acid (C₆H₅-CH=CH-COOH). ### Step 2: Hydrolysis of the Intermediate - **Hydrolysis**: The intermediate product A undergoes hydrolysis in the presence of water, leading to the formation of Cinnamic Acid. The hydrolysis can be represented as: \[ \text{A} + \text{H}_2\text{O} \rightarrow \text{Cinnamic Acid (C₆H₅-CH=CH-COOH)} \] ### Step 3: Addition of HBr to Cinnamic Acid - **Reactants**: Cinnamic Acid reacts with HBr. - **Mechanism**: The double bond in Cinnamic Acid acts as a nucleophile and attacks the electrophilic hydrogen (H⁺) from HBr. This leads to the formation of a carbocation. The bromide ion (Br⁻) then attacks the carbocation to form the final product B. The reaction can be represented as: \[ \text{Cinnamic Acid} + \text{HBr} \rightarrow \text{B} \] ### Step 4: Identify Product B - The product B formed after the addition of HBr to Cinnamic Acid is likely to be 3-Bromocinnamic Acid (C₆H₅-CHBr-CH=COOH). ### Final Answer The product B is **3-Bromocinnamic Acid (C₆H₅-CHBr-CH=COOH)**. ---

To solve the problem, we will follow the steps of the reaction sequence provided in the question. ### Step 1: Reaction of Benzaldehyde with Acetic Anhydride - **Reactants**: Benzaldehyde (PhCHO) and Acetic Anhydride ((CH₃CO)₂O) in the presence of Sodium Acetate (CH₃COONa). - **Mechanism**: The sodium acetate acts as a catalyst for the reaction, facilitating the formation of an intermediate product through a condensation reaction. This leads to the formation of an enol acetate. The reaction can be represented as: \[ \text{PhCHO} + \text{(CH}_3\text{CO)}_2\text{O} \xrightarrow{\text{CH}_3\text{COONa}} \text{A} \] ...
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