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Compare the pysical properties (mu,b.p, ...

Compare the pysical properties (`mu`,b.p, m.p., & stability) in the geometrical isomers of `CH_2-CH=CH-CN`.Choose from the following options:

A

`{:(mu,b.p,m.p.,"stability"),(cisgttrans,cisgttrans,transgt cis,transgtcis):}`

B

`{:(mu,b.p,m.p.,"stability"),(cisgttrans,transgtcis,transgt cis,transgtcis):}`

C

`{:(mu,b.p,m.p.,"stability"),(cisgttrans,cisgttrans,transgt cis,cisgttrans):}`

D

`{:(mu,b.p,m.p.,"stability"),(transgtcis,transgtcis,transgt cis,transgtcis):}`

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The correct Answer is:
To compare the physical properties (dipole moment, boiling point, melting point, and stability) of the geometrical isomers of `CH2=CH-CH-CN`, we will analyze the cis and trans forms of the compound step by step. ### Step 1: Draw the Structures 1. **Cis Isomer**: In the cis isomer, the CN group and the CH3 group are on the same side of the double bond. - Structure: ``` H CN \ / C / \ CH2 CH ``` 2. **Trans Isomer**: In the trans isomer, the CN group and the CH3 group are on opposite sides of the double bond. - Structure: ``` CN | C / \ CH2 CH \ H ``` ### Step 2: Compare Dipole Moments - **Cis Isomer**: The dipole moments from the CH3 to the CN will partially cancel out due to their orientation. The overall dipole moment will be lower. - **Trans Isomer**: The dipole moments from CH3 to CN will add up, resulting in a higher overall dipole moment. - **Conclusion**: The dipole moment of the trans isomer is greater than that of the cis isomer. ### Step 3: Compare Boiling Points - The boiling point is influenced by the dipole moment; higher dipole moments lead to stronger intermolecular forces. - **Cis Isomer**: Lower dipole moment results in weaker intermolecular forces, leading to a lower boiling point. - **Trans Isomer**: Higher dipole moment results in stronger intermolecular forces, leading to a higher boiling point. - **Conclusion**: The boiling point of the trans isomer is greater than that of the cis isomer. ### Step 4: Compare Melting Points - The melting point is affected by the packing efficiency of the molecules in the solid state. - **Cis Isomer**: Poor packing due to steric hindrance leads to a lower melting point. - **Trans Isomer**: Better packing due to less steric hindrance leads to a higher melting point. - **Conclusion**: The melting point of the trans isomer is greater than that of the cis isomer. ### Step 5: Compare Stability - Stability is influenced by steric hindrance. - **Cis Isomer**: The proximity of the CH3 and CN groups leads to steric hindrance, making it less stable. - **Trans Isomer**: The CH3 and CN groups are further apart, leading to less steric hindrance and greater stability. - **Conclusion**: The trans isomer is more stable than the cis isomer. ### Final Summary - **Dipole Moment**: Trans > Cis - **Boiling Point**: Trans > Cis - **Melting Point**: Trans > Cis - **Stability**: Trans > Cis

To compare the physical properties (dipole moment, boiling point, melting point, and stability) of the geometrical isomers of `CH2=CH-CH-CN`, we will analyze the cis and trans forms of the compound step by step. ### Step 1: Draw the Structures 1. **Cis Isomer**: In the cis isomer, the CN group and the CH3 group are on the same side of the double bond. - Structure: ``` H CN \ / ...
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