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Electrolysis of a solution of HSO(4)^(-)...

Electrolysis of a solution of `HSO_(4)^(-)` ions produces `S_(2)O_(8)^(-)`. Assuming `75%` current efficiency, what current should be employed to achieve a production rate of 1 mole of `S_(2)O_(8)^(-)` per hour?

A

71.48 A

B

35.7 A

C

142.96 A

D

285.93 A

Text Solution

Verified by Experts

The correct Answer is:
A

`2HSO_4^(-)toS_2O_8^(--)+2H^(+)+2e^(-)`
so required rate =1 mole / hr
2 mole of `e^(-)`/hr
`=(2xx96500)/(3600 sec)=(2xx965)/36A=53.61 A`
so required current =`4/3xx53.61 A=71.48 A`
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