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Co^(2+)(aq.)+SCN^(-)(aq.)to"Complex"(X) ...

`Co^(2+)(aq.)+SCN^(-)(aq.)to"Complex"(X)`
`Ni^(2+)(aq.)+"Dimethylglyoxime"overset(NH_4OH)to"Complex"(Y)`.
The coordination number of cobalt and nickel in complexes X and Y is four.
The IUPAC name of the complexes (X) and (Y) are respectively:

A

Tetrathiocyanato-S-cobalt(II) and Bis(dimethylglyoximate) nickel(II)

B

Tetrathiocyanato-S-cobaltate(II) and Bis(dimethylglymato) nickel(II)

C

Tetrathiocyanato-S-cobaltate(II) and Bis(dimethylglymato) nickelate(II)

D

Tetrathiocyanato-S-cobaltate(III) and Bis(dimethylglymato) nickel(II)

Text Solution

Verified by Experts

The correct Answer is:
B

`(X)=[Co(SCN)_4]^(2-),(Y)=[Co(dmg)_2]`
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