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For a solution obtained by mixing equal volumes of 0.02M KOH solution &0.2M B (weak diacidic base),`(K_(b_(1))=10^(-7) & K_(b_(2))=10^(-14))` . Find the pH of solution

A

`pH=12`

B

`[BH^(+)]=10^(-6)M`

C

`[BH_(2)^(2+)]=10^(-18)M`

D

All of these

Text Solution

Verified by Experts

`[OH^(-)]=(0.02)/(2)=0.01M:.pH=12`
`10^(-7)=(0.01[BH^(+)])/(0.1)rArr [BH^(+)]=10^(-6)M`
`10^(-7)=((0.01)^(2)[BH_(2)^(2+)])/(0.1)rArr [BH^(+)]=10^(-18)M`
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