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Which of the following mixture can act a...

Which of the following mixture can act as a buffer?

A

`H_(2)CO_(3)+NaOH (1.5:1 "molar ratio")`

B

`H_(2)CO_(3)+NaOH (1.5:2 "molar ratio")`

C

`NH_(4)OH+HCl(5:4"molar ratio")`

D

`NH_(4)OH+HCl (4:5 "molar ratio")`

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