Home
Class 12
CHEMISTRY
Arange the following in correct order of...

Arange the following in correct order of stability.
(i) `Ga' In, TI'` (ii) `As^(+5),Sb^(+5), B^(+5)`

Text Solution

AI Generated Solution

The correct Answer is:
To arrange the given elements in the correct order of stability, we need to consider the inert pair effect, which influences the stability of oxidation states in certain groups of the periodic table. ### Step-by-Step Solution: 1. **Identify the Elements and Their Oxidation States**: - For the first part: Ga^+, In^+, Tl^+ - For the second part: As^(+5), Sb^(+5), B^(+5) 2. **Understand the Inert Pair Effect**: - The inert pair effect refers to the tendency of the s-electrons (the outermost s-orbital electrons) to remain non-bonding in heavier elements of groups 13 and 15. This effect increases down the group, leading to a greater stability of lower oxidation states. 3. **Analyze Group 13 Elements (Ga, In, Tl)**: - Gallium (Ga) has a +1 oxidation state that is more stable than its +3 state due to the inert pair effect. - Indium (In) also shows a similar trend, but its +1 state is more stable than its +3 state as we move down the group. - Thallium (Tl) shows a strong inert pair effect, making its +1 state more stable than +3. - Therefore, the order of stability for Ga^+, In^+, Tl^+ is: - **Tl^+ > In^+ > Ga^+** 4. **Analyze Group 15 Elements (As^(+5), Sb^(+5), B^(+5))**: - In group 15, the stability of the +5 oxidation state decreases down the group due to the inert pair effect. - Boron (B) in the +5 state is more stable than Antimony (Sb) in the +5 state, which is more stable than Arsenic (As) in the +5 state. - Therefore, the order of stability for As^(+5), Sb^(+5), B^(+5) is: - **B^(+5) > Sb^(+5) > As^(+5)** 5. **Combine the Results**: - The final order of stability for both groups is: - **Tl^+ > In^+ > Ga^+** (for group 13) - **B^(+5) > Sb^(+5) > As^(+5)** (for group 15) ### Final Answer: 1. For Ga^+, In^+, Tl^+: **Tl^+ > In^+ > Ga^+** 2. For As^(+5), Sb^(+5), B^(+5): **B^(+5) > Sb^(+5) > As^(+5)**

To arrange the given elements in the correct order of stability, we need to consider the inert pair effect, which influences the stability of oxidation states in certain groups of the periodic table. ### Step-by-Step Solution: 1. **Identify the Elements and Their Oxidation States**: - For the first part: Ga^+, In^+, Tl^+ - For the second part: As^(+5), Sb^(+5), B^(+5) ...
Promotional Banner

Topper's Solved these Questions

  • PERIODIC TABLE & PERIODICITY

    RESONANCE ENGLISH|Exercise Exercise-2|1 Videos
  • PERIODIC TABLE & PERIODICITY

    RESONANCE ENGLISH|Exercise Exercise-3|1 Videos
  • PERIODIC TABLE & PERIODICITY

    RESONANCE ENGLISH|Exercise Exercise-1|1 Videos
  • P-BLOCK ELEMENTS (HALOGEN & NOBLE GASES)

    RESONANCE ENGLISH|Exercise APSP PART-3|22 Videos
  • QUALITATIVE ANALYSIS

    RESONANCE ENGLISH|Exercise INORGANIC CHMISTRY(Qualitative analysis)|35 Videos

Similar Questions

Explore conceptually related problems

Which of the following is correct order of stability:

Arrange the following in correct order of acidity (I) CaO , (II) SO_(2) , (III) SO_(3) , (IV) P_(2)O_(5)

Correct order of stability of following alkenes is

Which of the following is the correct order of stability of free radicals ?

Which of the following order is correct for thermal stability?

Consider the following carbanions: Correct decreasing order of stability is :

Express the following in the form a+i b :(5i)(-3/5i)

RESONANCE ENGLISH-PERIODIC TABLE & PERIODICITY-Exercise
  1. Which orbital electrons are known to shield the nuclear charge imprope...

    Text Solution

    |

  2. Pb^(+4)compounds are very good oxidising agents. Explain.

    Text Solution

    |

  3. Arange the following in correct order of stability. (i) Ga' In, TI' ...

    Text Solution

    |

  4. Explain why cation are smaller and anions larger in radii than their p...

    Text Solution

    |

  5. The density (in g ml^(−1) ) of a 3.60M sulphuric acid solution having...

    Text Solution

    |

  6. Find the concentration of solution in terms of weight percent if 40g o...

    Text Solution

    |

  7. Find the concentration of solution in terms of weight percent if 50g o...

    Text Solution

    |

  8. Find the concentration of solution in terms of weight percent if 20g o...

    Text Solution

    |

  9. Calculate the molar mass of H2SO4

    Text Solution

    |

  10. Calculate the molar mass of copper(II) carbonate.

    Text Solution

    |

  11. Calculate the molar mass of ammonia.

    Text Solution

    |

  12. Calculate the molar mass of sodium acetate.

    Text Solution

    |

  13. Explain the following a) Electronegatively of elements increase on m...

    Text Solution

    |

  14. The period number in the long form of the periodic table is equal to

    Text Solution

    |

  15. Which of the following statements about modern periodic table is incor...

    Text Solution

    |

  16. The elements in which electrons are progressilvely filled in 4f-orbial...

    Text Solution

    |

  17. Which of the following statements is not correct regarding hydrogen:

    Text Solution

    |

  18. Atomic number of Ag is 47. in the same group, the atomic numbers of el...

    Text Solution

    |

  19. In modern periodic table, the element with atomic number Z = 118 will ...

    Text Solution

    |

  20. The order of screeing effect of electrons of s,p,d and f orbitals of a...

    Text Solution

    |