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It is not possible to measure the atomic...

It is not possible to measure the atomic radius precisely since the electron cloud surrounding the atom does not have a sharp boundary. One practical approach to estimate the size of an atom of a non-metallic element is to measure the distance between two atoms when they are bound together by a single bond in a covalent molecule and then dividing by two. For metals we define the term "metallic radius" which is taken as half the inter nuclear distance separating the metal cores in the metallic crystal. Then van der waal's radius represents the over all size of the atoms which includes its valence shell in a non bonded situation. It is the half of the distance between two similar atoms in separate molecules in a solid. The atomic radius decreases across a period and increases down the group. Same trends are observed in case of ionic radius. Ionic radius of the species having same number of electrons depends on the number of protons in their nuclei. Sometimes, atomic and ionic radii give unexpected trends due to poor shielding of nuclear charge by `d`-and `f-`orbital electrons.
Now answer the following three questions:
Which of the following relations is correct, if considered for the same element.

A

`r_("vandewaal") gt r_("Covalent") gt r_("Metallic")`

B

`r_("Covalent") gt r_("Metallic") gt r_("Vanderwaal")`

C

`r_("Vanderwaal") gt r_("Metallic") gt r_("Covalent")`

D

`r_("Metallic") gt r_("Covalent") gt r_("Vanderwaal")`

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The correct Answer is:
To answer the question regarding the correct relationship between atomic and ionic radii for the same element, we can analyze the trends and definitions provided in the context of atomic structure and periodicity. ### Step-by-Step Solution: 1. **Understanding Atomic Radius**: The atomic radius is defined as the distance from the nucleus to the outermost shell of electrons. It is not a fixed value due to the electron cloud's nature, but it can be estimated through various methods, such as measuring bond lengths in covalent compounds. 2. **Understanding Ionic Radius**: The ionic radius refers to the size of an ion in a crystal lattice. For ions of the same element, the ionic radius can vary depending on whether the ion is positively charged (cation) or negatively charged (anion). Cations are generally smaller than their neutral atoms because they lose electrons, resulting in a stronger effective nuclear charge per electron. Anions are larger because they gain electrons, which increases electron-electron repulsion. 3. **Trends Across a Period**: As we move from left to right across a period in the periodic table, the atomic radius decreases due to the increasing nuclear charge, which pulls the electron cloud closer to the nucleus. This trend also applies to ionic radii, where cations decrease in size across a period. 4. **Trends Down a Group**: As we move down a group, the atomic radius increases because additional electron shells are added, which outweighs the effect of increasing nuclear charge. The same trend is observed for ionic radii, where both cations and anions increase in size down a group. 5. **Comparison of Atomic and Ionic Radii**: For the same element, the ionic radius of cations will always be smaller than the atomic radius of the neutral atom, while the ionic radius of anions will be larger than the atomic radius. This is due to the loss or gain of electrons affecting the electron cloud's size relative to the nucleus. ### Conclusion: The correct relationship for the same element is: - **Cation Radius < Atomic Radius < Anion Radius**
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It is not possible to measure the atomic radius prectsely since the electron cloub surrouding the atom does not have a sharp boundary. One practial approach to estimate the size of an atom of a non-metallic element is to measure the distance between two atoms when they are bound togther by a signle bond in a covalent molecule and then dividing by two. For metals we define the term "matellic radius" which is taken as half the internuclear distance separating the metal cores in the metallic crystal. Then van der waal's radius represents the over all size of the atoms which includes its valence shell in a non bonded situation. It is the half of the distance between two similar atoms in separate molecules in a solid. The atomis radius decreases across a period and increases down the group. Same trends are observed in case of ionic radius. Ionic radius of the species having same number of electrons depends on the number of protons in their nuclei. Sometimes, atomic and ionic radii give unexpected trends due to poor shielding of nuclear charge by d -and f- orbital electrons. Now answer the following three questions: Select the INCORRECT option regarding atomic//ionic sizes:

It is not possible to measure the atomic radius precisely since the electron cloud surrounding the atom does not have a sharp boundary. One practical approach to estimate the size of an atom of a non-metallic element is to measure the distance between two atoms when they are bound together by a single bond in a covalent molecule and then dividing by two. For metals we define the term "metallic radius" which is taken as half the inter nuclear distance separating the metal cores in the metallic crystal. Then van der waal's radius represents the over all size of the atoms which includes its valence shell in a non bonded situation. It is the half of the distance between two similar atoms in separate molecules in a solid. The atomic radius decreases across a period and increases down the group. Same trends are observed in case of ionic radius. Ionic radius of the species having same number of electrons depends on the number of protons in their nuclei. Sometimes, atomic and ionic radii give unexpected trends due to poor shielding of nuclear charge by d -and f- orbital electrons. Now answer the following three questions: K^(+), CI^(-), Ca^(2+), S^(2-) ions are isoelectronic. The decreasing order of their size is:

Which type of bond exists between the two boron atoms in a diborane molecule ?

The number of triple bonds between two C atoms in a molecule of ethyne is

A chemical bond between two atoms is:

When two atoms share electrons, they form a bond called

What type of force does exist between two atoms in an ionic bond?

The bond between two identical nonmetal atoms has a pair of electrons

The bond between two identical non-metal atoms has a pair of electrons:

The bond between two identical non-metal atoms has a pair of electrons:

RESONANCE ENGLISH-PERIODIC TABLE & PERIODICITY-Exercise
  1. Comprehension given below is followed by some multiple choice question...

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  2. In the modern periodic table, elements are arranged in order of increa...

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  3. It is not possible to measure the atomic radius precisely since the el...

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  4. It is not possible to measure the atomic radius precisely since the el...

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  5. It is not possible to measure the atomic radius prectsely since the el...

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  6. The periodicity is related to the electronic configuration. That is, a...

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  7. The periodicity is related to the electronic configuration. That is, a...

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  8. The periodicity is related to the electronic configuration. That is, a...

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  9. Arrange the following ions in order of their increasing size: Li^(+), ...

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  10. Compounds that formally contain Pb^(4+) are easily reduced to Pb^(+2) ...

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  11. Assertion: F atom has a less negative electron affinity than CI atom. ...

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  12. Ionic radii of :

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  13. The correct order of radii is:

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  14. Assertion: The first ionization energy of Be is greater than that of B...

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  15. The set representing the correct order of the first ionisation potenti...

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  16. Identify the least stable ion amongst the following :

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  17. Assertion (A) : Pb^(+4) compounds are stronger oxidiising agents than...

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  18. Among the following, how many elements show only one non-zero oxidatio...

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  19. Which one of the following ions has the highest value of ionic radius?

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  20. The formation of the oxide ion O^(2-) (g) requires first an exothermic...

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