Home
Class 12
CHEMISTRY
For the gaseous reaction K + F rarr K^(+...

For the gaseous reaction `K + F rarr K^(+) +F^(-), Deltah` was calculated to be `18.4` kcal/mol under conditions where the cations and anions were preverted from combining with each other. The ionisation enthalpy of `K` is 4.3 eV/atom. What is the electron gain enthalpy of F (in eV)? If your answer is `x` report it as `-2x`.

Text Solution

Verified by Experts

`{:(K(g)+F(g)rarrF^(-)(g)+K^(+)(g),,DeltaH =18.4 kCal =0.8 eV),(K(g)rarrK^(+)(g)+e^(-),,IE = 4.3 eV),(F(g)+e^(-)rarrF^(-)(g),,Delta_(eg)H =IE -DeltaH = 0.8 -4.3 =- 3.5 eV),(x =- 3.5,,),(2x =7,,):}`
Promotional Banner

Topper's Solved these Questions

  • PERIODIC TABLE & PERIODICITY

    RESONANCE ENGLISH|Exercise Exercise-3|1 Videos
  • P-BLOCK ELEMENTS (HALOGEN & NOBLE GASES)

    RESONANCE ENGLISH|Exercise APSP PART-3|22 Videos
  • QUALITATIVE ANALYSIS

    RESONANCE ENGLISH|Exercise INORGANIC CHMISTRY(Qualitative analysis)|35 Videos

Similar Questions

Explore conceptually related problems

For the gaseous reaction K+F rarrK^(o+)+F^(ɵ) Delta H = 19 kcal mol^(-1) under the condition when cations and anions are prevented by electrostatic separation from combining with each other. The IE_(1) of K is 4.3 eV . Calculate Delta_("eg")H^(ɵ) of F .

The energy released during conversion of million atoms of iodine in gaseous state to iodide ions in gaseous state is 4.9xx10^(-13)J . What is the electron gain enthalpy in eV/atom. [Report your answer by rounding it up to nearest whole number ]

For the reaction K(g)+F(g) +K^(o+)+F^(Theta) (separated ions DeltaH = 19 kcal mol^(-1) ), if the ionisation potential of K and the electron affinity of F^(Theta) have a geometric means of 3.88eV and IP gt EA , calculate the values fo ionisation potential and electron affinity.

The conservation of gaseous atoms K and F to K^(o+) and F^(ɵ) absorbs 0.85 eV of energy. If the IE and Delta_("eg")H^(ɵ) of K and F have magnitudes in the ratio of 7:6 , what is the electron gain enthalpy (Delta_("eg")H^(ɵ)) of fluorine ?

The conversion of gaseous atoms K and F to K^(o+) and F^(ɵ) absorbs 0.85 eV of energy. If the IE and Delta_("eg")H^(ɵ) of K and F have magnitudes in the ratio of 7:6 , what is the electron gain enthalpy (Delta_("eg")H^(ɵ)) of fluorine ?

If one zero of the quadratic polynomial f(x)=4x^2-8k x-9 is negative of the other, find the value of k .

For the reaction, X_(2)O_(4)(l)rarr2XO_(2)(g) , DeltaE=3.1Kcal , DeltaS=30cal//K at 300K . Hence DeltaG is

The lattice enthalpy of KI will be, if the enthalpy of (I) Delta_f H^- (KI) = -78.0 kcal mol^-1 (II) Ionisation energy of K to K^+ is 4.0 eV (III) Dissociation energy of I_2 is 28.0 kcal mol^-1 (IV) Sublimation energy of K is 20.0 kcal mol^-1 (V) Electron gain enthalpy for I to I^- is -70.0 kcal mol^-1 (VI) Sublimation energy of I_2 is 14.0 kcal mol^-1 (1 eV =23. 0 kcal mol^-1)

Gibbs-Helmoholtz equation relates the free energy change to the enthalpy and entropy changes of the process as (DeltaG)_(PT) = DeltaH - T DeltaS The magnitude of DeltaH does not change much with the change in temperature but the enrgy factor T DeltaS changes appreciably. Thus, spontaneity of a process depends very much on temperature. The enthalpy change for a certain reaction at 300K is -15.0 kcal mol^(-1) . The entropy change under these conditions is -7.2 cal K^(-) mol^(-1) . The free enegry change for the reaction and its spontaneous//nonspontaneous character will be

Use the following data to calculate Delta_("lattice") H^(Θ) " for " NaBr. Delta_("Sub")H^(Θ) for sodium metal = 108.4 kJ mol^(-1) , ionisation enthalpy of sodium = 496 kJ mol^(-1) , electron gain enthalpy of bromine = -325 kJ mol^(-1) , bond dissociation enthalpy of bromine = 192 kJ mol^(-1), Delta_(f) H^(Θ) " for " NaBr(s) = - 360.1 kJ mol^(-1)

RESONANCE ENGLISH-PERIODIC TABLE & PERIODICITY-Advanced Level Problems
  1. Most stable oxidation state of Thallium is +n. What is the value of n.

    Text Solution

    |

  2. Total number of elements which have more ionization energy as compare ...

    Text Solution

    |

  3. For the gaseous reaction K + F rarr K^(+) +F^(-), Deltah was calculate...

    Text Solution

    |

  4. How many elements are more electropositive than CI. B, N, O, C, S, ...

    Text Solution

    |

  5. EA(1) value of some group of p-Block elements are given: a, b, c…...

    Text Solution

    |

  6. EA(1) value of some group of p-Block elements ae given: a, b, c……...

    Text Solution

    |

  7. EA(1) value of some group of p-Block elements ae given: a, b, c……...

    Text Solution

    |

  8. The element whose electronic configuration is 1s^(2), 2s^(2)2p^(6), 3s...

    Text Solution

    |

  9. Oxygen shows +2 oxidation state is

    Text Solution

    |

  10. Which Group IIIA elements is expected to have physical and chemical pr...

    Text Solution

    |

  11. Which of the followig ions will show highest magnetic moment (Z values...

    Text Solution

    |

  12. Find the oxidation number of: Cr in K(2)Cr(2)O(7)

    Text Solution

    |

  13. Which of the following is the smallest in size ?

    Text Solution

    |

  14. Oxidation Number of Mn in [MnO(4)]^(-) is:

    Text Solution

    |

  15. The reduction potentials of Zn, Cu, Fe and Ag are in the increasing or...

    Text Solution

    |

  16. The formation of anion from a neutral atom X is favoured by:

    Text Solution

    |

  17. An isotone of .(32)^(76)Ge is- (a) .(32)^(77)Ge (b).(33)^(77)As (c).(...

    Text Solution

    |

  18. Which element of 3rd row has biggest atomic size?

    Text Solution

    |

  19. Which group of periodic table have large negative energy of activation...

    Text Solution

    |

  20. The species which has its fifth ionization potential equal to 340 V is...

    Text Solution

    |