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Amongst the following, the total number ...

Amongst the following, the total number of compounds soluble in concentrated `NH_(3)` solution is:
(A)`Ag_(2)CrO_(4)` , (B)`Cu(OH)_(2).CuSO_(4)` , ( C)`PbSO_(3)` , (D)`Al(OH)_(3)` , (E)`Ni(OH)_(2)`
(F)`Zn_(3)(PO_(4))_(2)` , (G)`BaSO_(4)` , (H)`Bi(OH)_(2)NO_(3)` , (I)`Mn(OH)_(2)`

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The correct Answer is:
To determine the total number of compounds that are soluble in concentrated NH₃ (ammonia) from the given options, we will analyze each compound based on their ability to form complexes with ammonia. ### Step-by-Step Solution: 1. **Identify the Compounds:** - (A) Ag₂CrO₄ - (B) Cu(OH)₂·CuSO₄ - (C) PbSO₃ - (D) Al(OH)₃ - (E) Ni(OH)₂ - (F) Zn₃(PO₄)₂ - (G) BaSO₄ - (H) Bi(OH)₂NO₃ - (I) Mn(OH)₂ 2. **Analyze Each Compound:** - **(A) Ag₂CrO₄:** - When Ag₂CrO₄ reacts with NH₃, it forms a complex (Ag(NH₃)₂)⁺ and is soluble in concentrated NH₃. - **Soluble.** - **(B) Cu(OH)₂·CuSO₄:** - This compound can form a complex with NH₃, resulting in the formation of [Cu(NH₃)₄]²⁺, thus it is soluble. - **Soluble.** - **(C) PbSO₃:** - PbSO₃ does not form a complex with NH₃ and is not soluble in concentrated NH₃. - **Not soluble.** - **(D) Al(OH)₃:** - Al(OH)₃ does not dissolve in concentrated NH₃; it is soluble in sodium hydroxide instead. - **Not soluble.** - **(E) Ni(OH)₂:** - Ni(OH)₂ can form a complex with NH₃, resulting in [Ni(NH₃)₆]²⁺, hence it is soluble. - **Soluble.** - **(F) Zn₃(PO₄)₂:** - Zn₃(PO₄)₂ can form a complex with NH₃, leading to the formation of [Zn(NH₃)₄]²⁺, thus it is soluble. - **Soluble.** - **(G) BaSO₄:** - BaSO₄ does not dissolve in concentrated NH₃; it is soluble in concentrated H₂SO₄ instead. - **Not soluble.** - **(H) Bi(OH)₂NO₃:** - Bi(OH)₂NO₃ does not form a complex with NH₃ and is not soluble. - **Not soluble.** - **(I) Mn(OH)₂:** - Mn(OH)₂ is also not directly soluble in concentrated NH₃; it is soluble in ammonium salts that release ammonia. - **Not soluble.** 3. **Count the Soluble Compounds:** - The compounds that are soluble in concentrated NH₃ are: - (A) Ag₂CrO₄ - (B) Cu(OH)₂·CuSO₄ - (E) Ni(OH)₂ - (F) Zn₃(PO₄)₂ Therefore, the total number of compounds soluble in concentrated NH₃ is **4**. ### Final Answer: The total number of compounds soluble in concentrated NH₃ solution is **4**.

To determine the total number of compounds that are soluble in concentrated NH₃ (ammonia) from the given options, we will analyze each compound based on their ability to form complexes with ammonia. ### Step-by-Step Solution: 1. **Identify the Compounds:** - (A) Ag₂CrO₄ - (B) Cu(OH)₂·CuSO₄ - (C) PbSO₃ ...
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