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IUPAC name of the compound BrCH(2)-under...

`IUPAC` name of the compound `BrCH_(2)-undersetunderset(CONH_(2))(|)(CH)-CO-CH_(2)-CH_(2)CH_(3)` is

A

`2`-Bromomethyl-`3`-oxohexanamide

B

`1`-Bromo-`2`-amido-`3`-oxohexane

C

`1`-Bromo-`2`-amido-n-propylketone

D

`3`-Bromo-`2`-proponyl-propanamide

Text Solution

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The correct Answer is:
To determine the IUPAC name of the compound `BrCH₂-CO-NH₂-(CH)-CO-CH₂-CH₂-CH₃`, we will follow a systematic approach to identify the longest carbon chain, the functional groups, and their positions. ### Step-by-Step Solution: 1. **Identify the Functional Groups**: - The compound has three functional groups: - An amide group (–CO–NH₂) - A keto group (C=O) - A bromo group (Br) 2. **Determine the Priority of Functional Groups**: - According to IUPAC nomenclature, the priority order of functional groups is as follows: 1. Amide (highest priority) 2. Ketone (C=O) 3. Bromo (lowest priority) 3. **Identify the Longest Carbon Chain**: - The longest continuous carbon chain that includes the amide group is 6 carbons long. We will number the chain starting from the end closest to the amide group. - The longest chain can be represented as: - C1 - C2 - C3 - C4 - C5 - C6 4. **Number the Carbon Chain**: - Numbering from the end nearest to the amide group: - C1: Amide group (–CO–NH₂) - C2: Bromo group (Br) - C3: Keto group (C=O) 5. **Assign Substituents and Their Positions**: - At C2, there is a bromo substituent (BrCH₂), which is referred to as bromomethyl. - At C3, there is a keto group, which is indicated by the prefix "oxo". 6. **Construct the Name**: - The base name for the 6-carbon chain is "hexane". - Since the primary functional group is an amide, the suffix will be "amide". - Combine the substituents with their positions: - 2-bromomethyl (from the bromo substituent) - 3-oxo (from the keto group) 7. **Final IUPAC Name**: - Combine all parts to form the complete name: - The IUPAC name of the compound is **2-bromomethyl-3-oxohexanamide**. ### Final Answer: **2-bromomethyl-3-oxohexanamide**
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