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Which of the following compounds will no...

Which of the following compounds will not give positive iodoform test.
Acetophenone, Benzophenone, `2`-Pentanone, `3`-Pentanone, Acetaldehyde,
`CH_(3)COCH_(3), (CH_(3))_(2)CHOH, (CH_(3)CH_(2))_(2)CH-OH, CH_(3)COOH, CH_(3)CONH_(2), CH_(3)COOCH_(3), CH_(3)COCl`

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To determine which compounds will not give a positive iodoform test, we need to identify those that do not contain the CH3C(=O) group or its derivatives. The iodoform test is positive for compounds that have a methyl ketone (RCOCH3) or a primary alcohol that can be oxidized to a methyl ketone. Let's analyze each compound step by step: 1. **Acetophenone (C6H5COCH3)**: - Structure: Contains CH3C(=O) group. - Conclusion: **Will give a positive iodoform test.** 2. **Benzophenone (C6H5COC6H5)**: - Structure: Does not contain CH3C(=O) group. - Conclusion: **Will NOT give a positive iodoform test.** 3. **2-Pentanone (CH3COCH2CH2CH3)**: - Structure: Contains CH3C(=O) group. - Conclusion: **Will give a positive iodoform test.** 4. **3-Pentanone (CH3CH2COCH2CH3)**: - Structure: Does not contain CH3C(=O) group. - Conclusion: **Will NOT give a positive iodoform test.** 5. **Acetaldehyde (CH3CHO)**: - Structure: Contains CH3C(=O) group. - Conclusion: **Will give a positive iodoform test.** 6. **Acetone (CH3COCH3)**: - Structure: Contains CH3C(=O) group. - Conclusion: **Will give a positive iodoform test.** 7. **2-Propanol ((CH3)2CHOH)**: - Structure: Can be oxidized to acetone (CH3COCH3). - Conclusion: **Will give a positive iodoform test.** 8. **2-Butanol ((CH3CH2)2CHOH)**: - Structure: Does not contain CH3C(=O) group. - Conclusion: **Will NOT give a positive iodoform test.** 9. **Acetic Acid (CH3COOH)**: - Structure: Contains CH3C(=O) group. - Conclusion: **Will give a positive iodoform test.** 10. **Acetamide (CH3CONH2)**: - Structure: Contains CH3C(=O) group. - Conclusion: **Will give a positive iodoform test.** 11. **Methyl Acetate (CH3COOCH3)**: - Structure: Contains CH3C(=O) group. - Conclusion: **Will give a positive iodoform test.** 12. **Acetyl Chloride (CH3COCl)**: - Structure: Contains CH3C(=O) group. - Conclusion: **Will give a positive iodoform test.** ### Summary of Compounds That Will NOT Give Positive Iodoform Test: - **Benzophenone** - **3-Pentanone** - **2-Butanol** ### Final Answer: The compounds that will not give a positive iodoform test are **Benzophenone, 3-Pentanone, and 2-Butanol**. ---

To determine which compounds will not give a positive iodoform test, we need to identify those that do not contain the CH3C(=O) group or its derivatives. The iodoform test is positive for compounds that have a methyl ketone (RCOCH3) or a primary alcohol that can be oxidized to a methyl ketone. Let's analyze each compound step by step: 1. **Acetophenone (C6H5COCH3)**: - Structure: Contains CH3C(=O) group. - Conclusion: **Will give a positive iodoform test.** ...
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