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Which of the following compound will not...

Which of the following compound will not give positive test with `NaHCO_(3)`.?
`{:("Phenol"",",CH_(3)COOH",",CH_(3)CH_(2)SO_(3)H",",CH_(3)C-=CH",",CH_(3)CH_(2)OH","),("Phthalic acid" ,"Salicylic acid" ",","Cinammic acid","Lactice acid",P-"Cresol"):}`

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The correct Answer is:
To determine which of the given compounds will not give a positive test with sodium bicarbonate (NaHCO₃), we need to understand the nature of the compounds listed and their reactivity with NaHCO₃. Sodium bicarbonate reacts with acids to produce carbon dioxide (CO₂) gas, which is the basis for the positive test. ### Step-by-Step Solution: 1. **Understanding NaHCO₃ Reaction**: - Sodium bicarbonate reacts with acids to produce CO₂ gas. Therefore, compounds that are acidic will give a positive test, while neutral or basic compounds will not. 2. **Analyzing Each Compound**: - **Phenol (C₆H₅OH)**: - Phenol is a weak acid but primarily behaves as a weak base. It does not produce CO₂ with NaHCO₃. - **Conclusion**: Will not give a positive test. - **Acetic Acid (CH₃COOH)**: - Acetic acid is a carboxylic acid and will react with NaHCO₃ to produce CO₂. - **Conclusion**: Will give a positive test. - **Ethane Sulfonic Acid (CH₃CH₂SO₃H)**: - This is a sulfonic acid, which is a strong acid. It will react with NaHCO₃ to produce CO₂. - **Conclusion**: Will give a positive test. - **Propyne (CH₃C≡CH)**: - Propyne is an alkyne and is not acidic. It will not react with NaHCO₃. - **Conclusion**: Will not give a positive test. - **Ethanol (CH₃CH₂OH)**: - Ethanol is an alcohol and is neutral in nature. It will not react with NaHCO₃. - **Conclusion**: Will not give a positive test. - **Phthalic Acid**: - Phthalic acid is a dicarboxylic acid and will react with NaHCO₃ to produce CO₂. - **Conclusion**: Will give a positive test. - **Salicylic Acid**: - Salicylic acid is also a carboxylic acid and will react with NaHCO₃ to produce CO₂. - **Conclusion**: Will give a positive test. - **Cinnamic Acid**: - Cinnamic acid is a carboxylic acid and will react with NaHCO₃ to produce CO₂. - **Conclusion**: Will give a positive test. - **Lactic Acid**: - Lactic acid is a carboxylic acid and will react with NaHCO₃ to produce CO₂. - **Conclusion**: Will give a positive test. - **p-Cresol**: - p-Cresol is similar to phenol and behaves as a weak base. It will not react with NaHCO₃. - **Conclusion**: Will not give a positive test. 3. **Final List of Compounds Not Giving Positive Test**: - The compounds that will not give a positive test with NaHCO₃ are: - Phenol - Propyne - Ethanol - p-Cresol ### Answer: The compounds that will not give a positive test with NaHCO₃ are **Phenol, Propyne, Ethanol, and p-Cresol**.

To determine which of the given compounds will not give a positive test with sodium bicarbonate (NaHCO₃), we need to understand the nature of the compounds listed and their reactivity with NaHCO₃. Sodium bicarbonate reacts with acids to produce carbon dioxide (CO₂) gas, which is the basis for the positive test. ### Step-by-Step Solution: 1. **Understanding NaHCO₃ Reaction**: - Sodium bicarbonate reacts with acids to produce CO₂ gas. Therefore, compounds that are acidic will give a positive test, while neutral or basic compounds will not. 2. **Analyzing Each Compound**: ...
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