Home
Class 12
CHEMISTRY
Using the van der Waals equation, calcul...

Using the van der Waals equation, calculate the pressure of `10.0mol NH_(3)` gas in a `10.0 L` vessel at `27^(@)C`.
`{:((P+n^(2)(a)/(V^(2)))(V-nb)=nRT,,a=4.2L^(2).atm//mol^(2),,b=0.037L//mol):}`

Text Solution

Verified by Experts

The correct Answer is:
`21.37atm`.

`(P+(n^(2)+4.2)/((10)^(2)) (V-nb) =nRT`
`(P+((10)^(2)xx4.2)/((10)^(2))) (10-10 xx 0.037) = 10 xx 0.082 xx 300`
Promotional Banner

Topper's Solved these Questions

  • GASEOUS STATE

    RESONANCE ENGLISH|Exercise Exercise-3|1 Videos
  • GASEOUS STATE

    RESONANCE ENGLISH|Exercise Exercise-2|1 Videos
  • FUNDAMENTAL CONCEPT

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Fundamental Concept )|40 Videos
  • HYDROCARBON

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Hydrocarbon)|50 Videos

Similar Questions

Explore conceptually related problems

Calculate the pressure exerted by 8.5 g of ammonia (NH_(3)) contained in a 0.5 L vessel at 300 K . For ammonia, a=4.0 atm L^(2)mol^(-2) , b=0.036 L mol^(-1) .

The van der Waals equation for one mol of CO_(2) gas at low pressure will be

The van der Waals equation for one mol of CO_(2) gas at low pressure will be

Calculate the pressure excerted by 5 mol of CO_(2) in 1 L vessel at 47^(@)C using van der Waals equation. (a=3.592 atm L^(2) mol^(-2), b=0.0427 L mol^(-1))

The van der Waal equation of gas is (P + (n^(2)a)/(V^(2))) (V - nb) = nRT

Calculate the pressure of 154 g carbon dioxide in a vessel of 2.0 L capacity at 30^(@)C , a = 648 L bar atm K^(-1) mol^(-1), b = 0.0427 L mol^(-1)

In the Van der Waals equation (P + (n^(2)a)/(V^(2))) (V-nb) = nRT , why is the term n^(2)a//V^(2) positive in sign.

Calculate the pressure exerted by one mole of methane in a 450 mL container at 25^@C using van der Waals' equation. What pressure will be predicted by ideal gas equation ? (Given : a = 2.253 " atm " L^2 mol^(-2), b = 0.0428 L mol^(-2), R =0.0821 L " atm " K^(-1) mol^(_1))

The van der Waals equation for one mole of a real gas can be written as (P+(a)/(v^(2))(V-b)=RT . For the gases H_(2), NH_(3), and CH_(4) , the value of 'a' "bar L"^(-2)"mol"^(-2) are 0.2453, 4.170 and 2.253 respectively. Which of the following can be inferred from the 'a' values?

RESONANCE ENGLISH-GASEOUS STATE-Exercise
  1. Calculate van der Waals constansts a and b if critical temperature and...

    Text Solution

    |

  2. Calculate the volume occupied by 2.0 mole of N(2) at 200K and 8.21 atm...

    Text Solution

    |

  3. Using the van der Waals equation, calculate the pressure of 10.0mol NH...

    Text Solution

    |

  4. The density of vapours of a substance of molar mass 18 g at 1 atm pres...

    Text Solution

    |

  5. One litre gas at 400K and 300atm pressure is compressed to a pressure ...

    Text Solution

    |

  6. Reduced temperature for benzene is 0.7277 and its reduced volume is 0....

    Text Solution

    |

  7. The values of a and b for oxygen are a = 1.360 atm litre^(2) mol^(-2) ...

    Text Solution

    |

  8. Consider a real gas placed in a container. If the intermolecular attra...

    Text Solution

    |

  9. The pressure of a real gas is less than the pressure of an ideal gas b...

    Text Solution

    |

  10. The critical temperature of water is higher than that of O(2) because ...

    Text Solution

    |

  11. Select incorrect statement:

    Text Solution

    |

  12. However great the pressure , a gas cannot be liquified above its :

    Text Solution

    |

  13. A real gas obeying van der Waals equation will resemble ideal gas , if...

    Text Solution

    |

  14. Graph depicting correct behaviour of ideal gas and H(2) gas will be (n...

    Text Solution

    |

  15. If temperature and volume are same, the pressure of a gas obeying van ...

    Text Solution

    |

  16. At 273 K temperature and 9 atm pressure, the compressibility for a gas...

    Text Solution

    |

  17. Positive deviation from ideal behaviour takes place because of :

    Text Solution

    |

  18. For non-zero value of force of attraction between gas molecular at lar...

    Text Solution

    |

  19. Compressibility factor for H(2) behaving as real gas is

    Text Solution

    |

  20. At low pressures, van der Waals' equation is written as (P+(a)/(V^(2))...

    Text Solution

    |