Home
Class 12
CHEMISTRY
One way of writing the equation of state...

One way of writing the equation of state for real gases is
`PV=RT[1+(B)/(V)+….]`
where `B` is a constant. Derive an approximate expression for `B` in terms of the van der Waals constants `a` and `b`.

A

`B = a - (b)/(RT)`

B

`B = b - (a)/(RT)`

C

`B = RT -(a)/(b)`

D

`B - (b)/(a)`

Text Solution

Verified by Experts

The correct Answer is:
B
Promotional Banner

Topper's Solved these Questions

  • GASEOUS STATE

    RESONANCE ENGLISH|Exercise Exercise-3|1 Videos
  • GASEOUS STATE

    RESONANCE ENGLISH|Exercise Exercise-2|1 Videos
  • FUNDAMENTAL CONCEPT

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Fundamental Concept )|40 Videos
  • HYDROCARBON

    RESONANCE ENGLISH|Exercise ORGANIC CHEMISTRY(Hydrocarbon)|50 Videos

Similar Questions

Explore conceptually related problems

One way of writing the equation of state for real gases is PV = RT [1+R/V+…] ? Where B is constant. Derive an approximate expression for B in terms of the van der Waals constant a and b.

Write the units of van der Waals' constant 'a' and 'b'.

The ratio of units of van der Waals constants a and b is

Units of van der Waal's constants 'a' and 'b' are respectively

The value of critical temperature in terms of van der Waals' constants a and b is given by

The value of critical temperature in terms of van der Waals' constants a and b is given by

The equation of state for real gas is given by ((p + (a)/(V^(2))(V - b) = RT . The dimension of the constant a is ………………. .

Which gas will liquefy easily ( a and b are van der Waals constants)?

Derive an expression for the van der Waals equation. Give the significance of the constants used in equation.

The ratio a/b (the terms used in van der Waals' equation) has the unit .

RESONANCE ENGLISH-GASEOUS STATE-Exercise
  1. What is the compressibility factor (Z) for 0.02 mole of a van der Waal...

    Text Solution

    |

  2. The van der Waals parameters for gases W, X, Y and Z are {:("Gas",a(...

    Text Solution

    |

  3. One way of writing the equation of state for real gases is PV=RT[1+(...

    Text Solution

    |

  4. The temperature at which real gases obey the ideal gas law over a wide...

    Text Solution

    |

  5. The temperature at which the second virial coefficient of real gas is ...

    Text Solution

    |

  6. Consider the following statements. If the van der Waal's parameters of...

    Text Solution

    |

  7. Select correct statements(s):

    Text Solution

    |

  8. For a real gas the P -V curve was experimentally plotted and it hed th...

    Text Solution

    |

  9. A real gas most closely approaches the behaviour of an ideal gas at:

    Text Solution

    |

  10. Calculate the compressibility factor for CO(2) if one mole of it occup...

    Text Solution

    |

  11. Virial equation is: PV(M)=RT[A+(B)/(V(M))+(C )/(V(M^(2)))+…], where A,...

    Text Solution

    |

  12. At Boyle’s temperature, the value of compressibility factor Z = (pV(m)...

    Text Solution

    |

  13. The critical density of the gas CO(2) is 0.44 g cm^(–3) at a certain t...

    Text Solution

    |

  14. The curve of pressure volume (PV) against pressure (P) of the gas at a...

    Text Solution

    |

  15. The vander waals constatn 'b' of a gas is 4 pi xx 10^(-4) L//mol. The ...

    Text Solution

    |

  16. For a fixed amount of real gas when a graph of z v//s p was plotted th...

    Text Solution

    |

  17. State True or False Decrease in Temperature may cause liquefaction o...

    Text Solution

    |

  18. Calculate molecular diameter for a gas if its molar exclued volume is ...

    Text Solution

    |

  19. If the ratio of PV(m) & RT for a real gas is (x)/(24) at a temp where ...

    Text Solution

    |

  20. 1 mol of C Cl(4) vapours at 77^(@)C occupies a volume of 35.0 L. If va...

    Text Solution

    |