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If the ratio of PV(m) & RT for a real ga...

If the ratio of `PV_(m) & RT` for a real gas is `(x)/(24)` at a temp where `((delP)/(delV_(m))) =0`. The find value of `10x`.

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To solve the problem, we need to find the value of \(10x\) given the ratio of \(\frac{PV_m}{RT} = \frac{x}{24}\) at a temperature where \(\frac{\partial P}{\partial V_m} = 0\). This condition indicates that we are at the critical point of the gas. ### Step-by-Step Solution: 1. **Understand the Critical Conditions**: At the critical point, the following relationships hold: - Critical temperature, \(T_c = \frac{8A}{27B}\) - Critical pressure, \(P_c = \frac{A}{27B^2}\) - Critical volume, \(V_c = 3B\) 2. **Set Up the Equation**: We know that at the critical point: \[ \frac{PV_m}{RT} = \frac{x}{24} \] Here, we can substitute \(P\), \(V_m\), and \(T\) with their critical values: \[ \frac{P_c \cdot V_c}{R \cdot T_c} = \frac{x}{24} \] 3. **Substitute the Critical Values**: Substitute \(P_c\), \(V_c\), and \(T_c\) into the equation: \[ \frac{\left(\frac{A}{27B^2}\right) \cdot (3B)}{R \cdot \left(\frac{8A}{27B}\right)} = \frac{x}{24} \] 4. **Simplify the Left Side**: Simplifying the left side: \[ \frac{\frac{3AB}{27B^2}}{\frac{8AR}{27B}} = \frac{3AB \cdot 27B}{27B^2 \cdot 8AR} = \frac{3}{8} \] 5. **Set the Equation Equal to \(\frac{x}{24}\)**: Now we have: \[ \frac{3}{8} = \frac{x}{24} \] 6. **Cross Multiply to Solve for \(x\)**: Cross-multiplying gives: \[ 3 \cdot 24 = 8x \implies 72 = 8x \implies x = \frac{72}{8} = 9 \] 7. **Calculate \(10x\)**: Finally, we need to find \(10x\): \[ 10x = 10 \cdot 9 = 90 \] ### Final Answer: Thus, the value of \(10x\) is \(90\). ---
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